β-1,3-Glucan schizophyllan can act as a one-dimensional host to arrange icosahedral carboranes

Munenori Numata; Shingo Tamesue; Takeshi Nagasaki; Kazuo Sakurai; Seiji Shinkai

doi:10.1246/cl.2007.668

β-1,3-Glucan schizophyllan can act as a one-dimensional host to arrange icosahedral carboranes

Munenori Numata, Shingo Tamesue, Takeshi Nagasaki, Kazuo Sakurai, Seiji Shinkai

Institute for Advanced Study

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

We here demonstrate that schizophyllan (SPG: one kind of β-1,3-glucans)/m-carborane nanocomposites can be easily created in a supramolecular manner by utilizing the unique wrapping capability of SPG. TEM observations revealed that incorporated m-carborane molecules adopt continuous one-dimensional (1-D) arrangement in the SPG hydrophobic cavity. We believe that the present system can provide a novel concept not only for the separation of carborane isomers and the construction of one-dimensional architectures but also for the new formulation of boron neutron capture therapy (BNCT) agents.

Original language	English
Pages (from-to)	668-669
Number of pages	2
Journal	Chemistry Letters
Volume	36
Issue number	5
DOIs	https://doi.org/10.1246/cl.2007.668
Publication status	Published - May 5 2007

All Science Journal Classification (ASJC) codes

Chemistry(all)

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10.1246/cl.2007.668

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abstract = "We here demonstrate that schizophyllan (SPG: one kind of β-1,3-glucans)/m-carborane nanocomposites can be easily created in a supramolecular manner by utilizing the unique wrapping capability of SPG. TEM observations revealed that incorporated m-carborane molecules adopt continuous one-dimensional (1-D) arrangement in the SPG hydrophobic cavity. We believe that the present system can provide a novel concept not only for the separation of carborane isomers and the construction of one-dimensional architectures but also for the new formulation of boron neutron capture therapy (BNCT) agents.",

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AU - Numata, Munenori

AU - Tamesue, Shingo

AU - Nagasaki, Takeshi

AU - Sakurai, Kazuo

AU - Shinkai, Seiji

PY - 2007/5/5

Y1 - 2007/5/5

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