β-(Ethynylbenzoic acid)-substituted push-pull porphyrins: DSSC dyes prepared by a direct palladium-catalyzed alkynylation reaction

Masatoshi Ishida; Deasub Hwang; Young Bean Koo; Jooyoung Sung; Dong Young Kim; Jonathan L. Sessler; Dongho Kim

doi:10.1039/c3cc44847a

β-(Ethynylbenzoic acid)-substituted push-pull porphyrins: DSSC dyes prepared by a direct palladium-catalyzed alkynylation reaction

Masatoshi Ishida, Deasub Hwang, Young Bean Koo, Jooyoung Sung, Dong Young Kim, Jonathan L. Sessler, Dongho Kim

Applied Chemistry

Research output: Contribution to journal › Article › peer-review

47 Citations (Scopus)

Abstract

The palladium-catalyzed oxidative alkynylation of β-borylated porphyrins allows for concise preparation of push-pull structured ethynylbenzoic acid porphyrin derivatives. The resulting β-singly- and doubly-substituted porphyrin dyes are regarded as isomeric derivatives of the corresponding meso-substituted reference systems, and were found to give rise to nearly equal power conversion efficiencies when analyzed in DSSCs.

Original language	English
Pages (from-to)	9164-9166
Number of pages	3
Journal	Chemical Communications
Volume	49
Issue number	80
DOIs	https://doi.org/10.1039/c3cc44847a
Publication status	Published - Sept 12 2013

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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T2 - DSSC dyes prepared by a direct palladium-catalyzed alkynylation reaction

AU - Ishida, Masatoshi

AU - Hwang, Deasub

AU - Koo, Young Bean

AU - Sung, Jooyoung

AU - Kim, Dong Young

AU - Sessler, Jonathan L.

AU - Kim, Dongho

PY - 2013/9/12

Y1 - 2013/9/12

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AB - The palladium-catalyzed oxidative alkynylation of β-borylated porphyrins allows for concise preparation of push-pull structured ethynylbenzoic acid porphyrin derivatives. The resulting β-singly- and doubly-substituted porphyrin dyes are regarded as isomeric derivatives of the corresponding meso-substituted reference systems, and were found to give rise to nearly equal power conversion efficiencies when analyzed in DSSCs.

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ER -

β-(Ethynylbenzoic acid)-substituted push-pull porphyrins: DSSC dyes prepared by a direct palladium-catalyzed alkynylation reaction

Abstract

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