β-functionalization of 5, 15-diazaporphyrins with phosphorus, oxygen, and sulfur-containing substituents

Takuma Sugai, Mao Minoura, Haruyuki Nakano, Yoshihiro Matano

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

The β-functionalization of 5, 15-diazaporphyrins (DAPs) with phosphoryl, phenoxy, sulfanyl, and sulfonyl groups was achieved by either cross-coupling or aromatic nucleophilic substitution reactions of β-bromo- and β, β′-dibromo-DAPs. The heteroatom-containing functional groups at the β- positions strongly affected the redox properties of the DAP π-systems.

Original languageEnglish
Pages (from-to)1264-1266
Number of pages3
JournalBulletin of the Chemical Society of Japan
Volume91
Issue number8
DOIs
Publication statusPublished - Jan 1 2018

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Sulfur
Phosphorus
Functional groups
Substitution reactions
Oxygen
Oxidation-Reduction

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

Cite this

β-functionalization of 5, 15-diazaporphyrins with phosphorus, oxygen, and sulfur-containing substituents. / Sugai, Takuma; Minoura, Mao; Nakano, Haruyuki; Matano, Yoshihiro.

In: Bulletin of the Chemical Society of Japan, Vol. 91, No. 8, 01.01.2018, p. 1264-1266.

Research output: Contribution to journalArticle

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