Abstract
(Chemical Equation Presented) Making the right substitution: A remarkable acceleration effect of phenyl-substituted silyl groups in hydroalumination and carbolithiation reactions of propargylic alcohols (see formula) is described. The results show that an aryl silyl group can act not only as a protecting group but also as an activating group of the alkynyl moiety. This work provides an efficient group-selective approach to multifunctionalized alkenes.
| Original language | English |
|---|---|
| Pages (from-to) | 232-234 |
| Number of pages | 3 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 45 |
| Issue number | 2 |
| DOIs | |
| Publication status | Published - Dec 23 2005 |
| Externally published | Yes |
All Science Journal Classification (ASJC) codes
- Catalysis
- Chemistry(all)