μ,-hydroxo-μ,-phenolato dinuclear zinc(II) and nickel(II) complexes derived from dinucleating compartmental ligands of "end-off" type: Synthesis, structures, and properties

Kanako Matsufuji; Hitomi Shiraishi; Yuji Miyasato; Takuya Shiga; Masaaki Ohba; Takushi Yokoyama; Hisashi Okawa

doi:10.1246/bcsj.78.851

μ,-hydroxo-μ,-phenolato dinuclear zinc(II) and nickel(II) complexes derived from dinucleating compartmental ligands of "end-off" type: Synthesis, structures, and properties

Kanako Matsufuji, Hitomi Shiraishi, Yuji Miyasato, Takuya Shiga, Masaaki Ohba, Takushi Yokoyama, Hisashi Okawa

Inorganic and Analytical Chemistry

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19 Citations (Scopus)

Abstract

Some dinucleating compartmental ligands of "end-off" type, 2,6-bis{N-[(2-dimethylamino)ethyl]iminomethyl}-4-methylphenol (HL¹), 2,6-bis{N-(2-pyridylethyl)iminomethyl}-4-methylphenol (HL²), and 2,6-bis{N,N-di(2-pyridylmethyl)aminomethyl}-4-methylphenol (HL³), have afforded the following dinuclear Zn(II) and Ni(II) complexes: [Zn ₂(L¹)(OH)(py)₂](ClO₄)₂ (1), [Zn₂(L²)(OH)(py)₃](ClO₄) ₂ (2), [Zn₂(L³)(OH)](ClO₄) ₂ (3), [Ni₂(L¹)(OH)(py)₂](ClO ₄)₂ (4), and [Ni₂(L²)(OH)(py) ₄](ClO₄)₂ (5). X-ray crystallographic studies for 1·Pr²OH, 2·0.5Pr²OH, 3·MeCN, 4·py, and 5 indicate that they have a dinuclear core doubly bridged by the endogenous phenolic oxygen of each compartmental ligand and by exogenous hydroxide oxygen. Physicochemical properties of 1-5 are studied.

Original language	English
Pages (from-to)	851-858
Number of pages	8
Journal	Bulletin of the Chemical Society of Japan
Volume	78
Issue number	5
DOIs	https://doi.org/10.1246/bcsj.78.851
Publication status	Published - May 15 2005

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Chemistry(all)

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10.1246/bcsj.78.851

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μ,-hydroxo-μ,-phenolato dinuclear zinc(II) and nickel(II) complexes derived from dinucleating compartmental ligands of "end-off" type: Synthesis, structures, and properties. / Matsufuji, Kanako; Shiraishi, Hitomi; Miyasato, Yuji et al.
In: Bulletin of the Chemical Society of Japan, Vol. 78, No. 5, 15.05.2005, p. 851-858.

Research output: Contribution to journal › Article › peer-review

Matsufuji, K, Shiraishi, H, Miyasato, Y, Shiga, T, Ohba, M, Yokoyama, T & Okawa, H 2005, 'μ,-hydroxo-μ,-phenolato dinuclear zinc(II) and nickel(II) complexes derived from dinucleating compartmental ligands of "end-off" type: Synthesis, structures, and properties', Bulletin of the Chemical Society of Japan, vol. 78, no. 5, pp. 851-858. https://doi.org/10.1246/bcsj.78.851

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title = "μ,-hydroxo-μ,-phenolato dinuclear zinc(II) and nickel(II) complexes derived from dinucleating compartmental ligands of {"}end-off{"} type: Synthesis, structures, and properties",

abstract = "Some dinucleating compartmental ligands of {"}end-off{"} type, 2,6-bis{N-[(2-dimethylamino)ethyl]iminomethyl}-4-methylphenol (HL1), 2,6-bis{N-(2-pyridylethyl)iminomethyl}-4-methylphenol (HL2), and 2,6-bis{N,N-di(2-pyridylmethyl)aminomethyl}-4-methylphenol (HL3), have afforded the following dinuclear Zn(II) and Ni(II) complexes: [Zn 2(L1)(OH)(py)2](ClO4)2 (1), [Zn2(L2)(OH)(py)3](ClO4) 2 (2), [Zn2(L3)(OH)](ClO4) 2 (3), [Ni2(L1)(OH)(py)2](ClO 4)2 (4), and [Ni2(L2)(OH)(py) 4](ClO4)2 (5). X-ray crystallographic studies for 1·Pr2OH, 2·0.5Pr2OH, 3·MeCN, 4·py, and 5 indicate that they have a dinuclear core doubly bridged by the endogenous phenolic oxygen of each compartmental ligand and by exogenous hydroxide oxygen. Physicochemical properties of 1-5 are studied.",

author = "Kanako Matsufuji and Hitomi Shiraishi and Yuji Miyasato and Takuya Shiga and Masaaki Ohba and Takushi Yokoyama and Hisashi Okawa",

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doi = "10.1246/bcsj.78.851",

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T1 - μ,-hydroxo-μ,-phenolato dinuclear zinc(II) and nickel(II) complexes derived from dinucleating compartmental ligands of "end-off" type

T2 - Synthesis, structures, and properties

AU - Matsufuji, Kanako

AU - Shiraishi, Hitomi

AU - Miyasato, Yuji

AU - Shiga, Takuya

AU - Ohba, Masaaki

AU - Yokoyama, Takushi

AU - Okawa, Hisashi

PY - 2005/5/15

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N2 - Some dinucleating compartmental ligands of "end-off" type, 2,6-bis{N-[(2-dimethylamino)ethyl]iminomethyl}-4-methylphenol (HL1), 2,6-bis{N-(2-pyridylethyl)iminomethyl}-4-methylphenol (HL2), and 2,6-bis{N,N-di(2-pyridylmethyl)aminomethyl}-4-methylphenol (HL3), have afforded the following dinuclear Zn(II) and Ni(II) complexes: [Zn 2(L1)(OH)(py)2](ClO4)2 (1), [Zn2(L2)(OH)(py)3](ClO4) 2 (2), [Zn2(L3)(OH)](ClO4) 2 (3), [Ni2(L1)(OH)(py)2](ClO 4)2 (4), and [Ni2(L2)(OH)(py) 4](ClO4)2 (5). X-ray crystallographic studies for 1·Pr2OH, 2·0.5Pr2OH, 3·MeCN, 4·py, and 5 indicate that they have a dinuclear core doubly bridged by the endogenous phenolic oxygen of each compartmental ligand and by exogenous hydroxide oxygen. Physicochemical properties of 1-5 are studied.

AB - Some dinucleating compartmental ligands of "end-off" type, 2,6-bis{N-[(2-dimethylamino)ethyl]iminomethyl}-4-methylphenol (HL1), 2,6-bis{N-(2-pyridylethyl)iminomethyl}-4-methylphenol (HL2), and 2,6-bis{N,N-di(2-pyridylmethyl)aminomethyl}-4-methylphenol (HL3), have afforded the following dinuclear Zn(II) and Ni(II) complexes: [Zn 2(L1)(OH)(py)2](ClO4)2 (1), [Zn2(L2)(OH)(py)3](ClO4) 2 (2), [Zn2(L3)(OH)](ClO4) 2 (3), [Ni2(L1)(OH)(py)2](ClO 4)2 (4), and [Ni2(L2)(OH)(py) 4](ClO4)2 (5). X-ray crystallographic studies for 1·Pr2OH, 2·0.5Pr2OH, 3·MeCN, 4·py, and 5 indicate that they have a dinuclear core doubly bridged by the endogenous phenolic oxygen of each compartmental ligand and by exogenous hydroxide oxygen. Physicochemical properties of 1-5 are studied.

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μ,-hydroxo-μ,-phenolato dinuclear zinc(II) and nickel(II) complexes derived from dinucleating compartmental ligands of "end-off" type: Synthesis, structures, and properties

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