100% phosphorescence quantum efficiency of Ir (III) complexes in organic semiconductor films

Yuichiro Kawamura, Kenichi Goushi, Jason Brooks, Julie J. Brown, Hiroyuki Sasabe, Chihaya Adachi

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Abstract

We demonstrate that three Ir (III) complexes used as principal dopants in organic electrophosphorescent diodes have very high photoluminescence quantum efficiency (ηPL) in a solid-state film. The green emitting complex, fac-tris(2-phenylpyridinato)iridium(III) [Ir (ppy)3], the red-emitting bis [2- (2′ -benzothienyl) pyridinato-N, C3′] (acetylacetonato)iridium(III) [Btp2 Ir(acac)], and the blue complex bis [(4,6-difluorophenyl) pyridinato-N, C2] (picolinato) iridium(III) (FIrpic) were prepared as codeposited films of varying concentration with 4, 4′ -bis (N-carbazolyl) -2, 2′ -biphenyl, a commonly used host material. The maximum ηPL values for Ir (ppy)3, Btp2 Ir(acac), and FIrpic were, respectively, 97%±2% (at 1.5 mol%), 51%±1% (at 1.4 mol%), and 78%±1% (at 15 mol%). Furthermore, we also observed that the maximum ηPL of FIrpic reached 99%±1% when doped into the high triplet energy host, m-bis (N-carbazolyl) benzene, at an optimal concentration of 1.2 mol%.

Original languageEnglish
Article number071104
Pages (from-to)1-3
Number of pages3
JournalApplied Physics Letters
Volume86
Issue number7
DOIs
Publication statusPublished - Feb 14 2005

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organic semiconductors
phosphorescence
iridium
quantum efficiency
diodes
benzene
solid state
photoluminescence
energy

All Science Journal Classification (ASJC) codes

  • Physics and Astronomy (miscellaneous)

Cite this

100% phosphorescence quantum efficiency of Ir (III) complexes in organic semiconductor films. / Kawamura, Yuichiro; Goushi, Kenichi; Brooks, Jason; Brown, Julie J.; Sasabe, Hiroyuki; Adachi, Chihaya.

In: Applied Physics Letters, Vol. 86, No. 7, 071104, 14.02.2005, p. 1-3.

Research output: Contribution to journalArticle

Kawamura, Yuichiro ; Goushi, Kenichi ; Brooks, Jason ; Brown, Julie J. ; Sasabe, Hiroyuki ; Adachi, Chihaya. / 100% phosphorescence quantum efficiency of Ir (III) complexes in organic semiconductor films. In: Applied Physics Letters. 2005 ; Vol. 86, No. 7. pp. 1-3.
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