@article{4471f2b590604b25af00cf03635028ff,
title = "1,2-Insertion reactions of alkynes into Ge-C bonds of arylbromogermylene",
abstract = "1,2-Insertion reactions of alkynes into the Ge-C bonds in dibromodigermenes afford stable crystalline bromovinylgermylenes. In contrast to previously reported Lewis-base-supported vinylgermylenes, the bromovinylgermylene obtained from reaction of the bromogermylene with 3-hexyneviasuch an 1,2-insertion is a donor-free monomer. A feasible reaction mechanism, proposed on the basis of the observed experimental results in combination with theoretical calculations, suggests that the [1+2]-cycloadduct and the insertion product are the kinetic and thermodynamic product, respectively.",
author = "Tomohiro Sugahara and {Espinosa Ferao}, Arturo and {Rey Planells}, Alicia and Guo, {Jing Dong} and Shin Aoyama and Kazunobu Igawa and Katsuhiko Tomooka and Takahiro Sasamori and Daisuke Hashizume and Shigeru Nagase and Norihiro Tokitoh",
note = "Funding Information: This work was financially supported by JSPS KAKENHI grants JP15H03777, JP18K05078, and JP19H02705 from MEXT (Japan), a Grant-in-Aid for Research at Nagoya City University, the Collaborative Research Program of the Institute for Chemical Research at Kyoto University (2018-22), JST CREST Grant (No. JPMJCR19R4), Fujimori Science and Technology Foundation, the DAIKO FOUNDATION, Mitsubishi Gas Chemical, as well as JURC, IRCCS, and KURCA (Kyoto University). We acknowledge the generous assistance of the Research Equipment Sharing Center at Nagoya City University and the computation centre at Servicio de C{\'a}lculo Cient{\'i}fico (SCC-University of Murcia) for their technical support as well as the computational resources used. T. Sugahara gratefully acknowledges support from a grant-in-aid for JSPS fellows (JP16J05501). We are grateful to Materials Characterization Support Team, RIKEN Center for Emergent Matter Science for the elemental analysis. We would also like to thank Mr. Toshiaki Noda and Ms. Hideko Natsume (Nagoya University) for the expert manufacturing of custom-tailored glassware. Funding Information: This work was financially supported by JSPS KAKENHI grants JP15H03777, JP18K05078, and JP19H02705 from MEXT (Japan), a Grant-in-Aid for Research at Nagoya City University, the Collaborative Research Program of the Institute for Chemical Research at Kyoto University (2018-22), JST CREST Grant (No. JPMJCR19R4), Fujimori Science and Technology Foundation, the DAIKO FOUNDATION, Mitsubishi Gas Chemical, as well as JURC, IRCCS, and KURCA (Kyoto University). We acknowledge the generous assistance of the Research Equipment Sharing Center at Nagoya City University and the computation centre at Servicio de C?lculo Cient?fico (SCC-University of Murcia) for their technical support as well as the computational resources used. T. Sugahara gratefully acknowledges support from a grant-in-aid for JSPS fellows (JP16J05501). We are grateful to Materials Characterization Support Team, RIKEN Center for Emergent Matter Science for the elemental analysis. We would also like to thank Mr. Toshiaki Noda and Ms. Hideko Natsume (Nagoya University) for the expert manufacturing of custom-tailored glassware. Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2020.",
year = "2020",
month = jun,
day = "7",
doi = "10.1039/d0dt01223h",
language = "English",
volume = "49",
pages = "7189--7196",
journal = "Dalton Transactions",
issn = "1477-9226",
publisher = "Royal Society of Chemistry",
number = "21",
}