1,4-Addition reactions of hexafluoro-1,3-butadiene

Richard D. Chambers, Shin Nishimura, Graham Sandford

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

Polymerisation of hexafluoro-1,3-butadiene (1) using γ-rays as initiator is dependent on the solvent, and tetrahydrofuran is incorporated into a polymer. It is concluded from solid-state NMR data that polymers arise mainly from 1,4-addition to 1. Bromination of 1 occurs readily in the dark giving a product also arising from a 1,4-addition process.

Original languageEnglish
Pages (from-to)187-190
Number of pages4
JournalJournal of Fluorine Chemistry
Volume96
Issue number2
DOIs
Publication statusPublished - Jul 4 1999
Externally publishedYes

Fingerprint

Addition reactions
butadiene
Polymers
polymer
bromination
Halogenation
polymers
initiators
tetrahydrofuran
polymerization
Polymerization
nuclear magnetic resonance
rays
Nuclear magnetic resonance
solid state
products
1,3-butadiene
product

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Environmental Chemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

Cite this

1,4-Addition reactions of hexafluoro-1,3-butadiene. / Chambers, Richard D.; Nishimura, Shin; Sandford, Graham.

In: Journal of Fluorine Chemistry, Vol. 96, No. 2, 04.07.1999, p. 187-190.

Research output: Contribution to journalArticle

Chambers, Richard D. ; Nishimura, Shin ; Sandford, Graham. / 1,4-Addition reactions of hexafluoro-1,3-butadiene. In: Journal of Fluorine Chemistry. 1999 ; Vol. 96, No. 2. pp. 187-190.
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