1,4-Remote stereocontrol via asymmetric [2,3]-Wittig rearrangements

Katsuhiko Tomooka, Ping Huai Keong, Takeshi Nakai

Research output: Contribution to journalArticle

12 Citations (Scopus)

Abstract

The carbanion rearrangement of the propargylic ether of the β-(1-alkoxyethyl) allyl alcohol was found to proceed with a high degree of either 1,4-syn or 1,4-anti selection by virtue of the proper choice of the combination of the alkoxy group with the solvent used.

Original languageEnglish
Pages (from-to)2789-2792
Number of pages4
JournalTetrahedron Letters
Volume36
Issue number16
DOIs
Publication statusPublished - Apr 17 1995
Externally publishedYes

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Ether
alkoxyl radical
allyl alcohol

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

Cite this

1,4-Remote stereocontrol via asymmetric [2,3]-Wittig rearrangements. / Tomooka, Katsuhiko; Keong, Ping Huai; Nakai, Takeshi.

In: Tetrahedron Letters, Vol. 36, No. 16, 17.04.1995, p. 2789-2792.

Research output: Contribution to journalArticle

Tomooka, Katsuhiko ; Keong, Ping Huai ; Nakai, Takeshi. / 1,4-Remote stereocontrol via asymmetric [2,3]-Wittig rearrangements. In: Tetrahedron Letters. 1995 ; Vol. 36, No. 16. pp. 2789-2792.
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