TY - JOUR
T1 - 1D cerium(III) coordination polymer with pivalate bridges
T2 - Synthesis, structure and magnetic properties
AU - Akhtar, Muhammad Nadeem
AU - Mateen, Muhammad
AU - Sadakiyo, Masaaki
AU - Warsi, Muhammad Farooq
AU - AlDamen, Murad A.
AU - Song, You
PY - 2017/8/5
Y1 - 2017/8/5
N2 - In the present work, synthesis, characterization, and properties of a new 1D-polymeric chain of [Ce(piv)3(MeOH)2]n (1D-Ce) are described. This polymeric structure was synthesized via reaction of Ce(NO3)3·6H2O with pivalic acid in presence of triethylamine. Crystal structure consists of cerium coordinated to eight oxygen atoms from five pivalate and two methanol moieties. Magnetic studies on the complex revealed a strong antiferromagnetic interaction between CeIII ions in the 1D chain.
AB - In the present work, synthesis, characterization, and properties of a new 1D-polymeric chain of [Ce(piv)3(MeOH)2]n (1D-Ce) are described. This polymeric structure was synthesized via reaction of Ce(NO3)3·6H2O with pivalic acid in presence of triethylamine. Crystal structure consists of cerium coordinated to eight oxygen atoms from five pivalate and two methanol moieties. Magnetic studies on the complex revealed a strong antiferromagnetic interaction between CeIII ions in the 1D chain.
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U2 - 10.1016/j.molstruc.2017.03.068
DO - 10.1016/j.molstruc.2017.03.068
M3 - Article
AN - SCOPUS:85016488553
SN - 0022-2860
VL - 1141
SP - 170
EP - 175
JO - Journal of Molecular Structure
JF - Journal of Molecular Structure
ER -