1D cerium(III) coordination polymer with pivalate bridges: Synthesis, structure and magnetic properties

Muhammad Nadeem Akhtar, Muhammad Mateen, Masaaki Sadakiyo, Muhammad Farooq Warsi, Murad A. AlDamen, You Song

    Research output: Contribution to journalArticlepeer-review

    3 Citations (Scopus)

    Abstract

    In the present work, synthesis, characterization, and properties of a new 1D-polymeric chain of [Ce(piv)3(MeOH)2]n (1D-Ce) are described. This polymeric structure was synthesized via reaction of Ce(NO3)3·6H2O with pivalic acid in presence of triethylamine. Crystal structure consists of cerium coordinated to eight oxygen atoms from five pivalate and two methanol moieties. Magnetic studies on the complex revealed a strong antiferromagnetic interaction between CeIII ions in the 1D chain.

    Original languageEnglish
    Pages (from-to)170-175
    Number of pages6
    JournalJournal of Molecular Structure
    Volume1141
    DOIs
    Publication statusPublished - Aug 5 2017

    All Science Journal Classification (ASJC) codes

    • Analytical Chemistry
    • Spectroscopy
    • Organic Chemistry
    • Inorganic Chemistry

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