(2,2′-Bipyridine)bis(N-methyl-4,4′-bi-pyridinium)platinum(II) tetraperchlorate

Ken Sakai, Manabu Osada, Yoshimi Yokoyama, Yasushi Tomita, Taro Tsubomura

Research output: Contribution to journalArticlepeer-review

7 Citations (Scopus)

Abstract

In the title compound, [Pt(C10H8N2)(C 11H11N2)2](ClO4) 4, the square-planar PtN4 coordination geometry is slightly deformed, with the coordinated N atom of one of the N-methyl-4,4′-bipyridinium (MQ) ligands 0.262 (8) Å out of the plane defined by the rest of the coordinated N atoms and the Pt atom. The exceptional behavior of this MQ ligand is interpreted in terms of the electrostatic interactions between the positively charged MQ ligands and the perchlorate anions, where the N(MQ)⋯O(perchlorate) distances are in the range 2.932 (12)-3.259 (13) Å.

Original languageEnglish
Pages (from-to)m512-m514
JournalActa Crystallographica Section E: Structure Reports Online
Volume59
Issue number7
DOIs
Publication statusPublished - Jul 1 2003
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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