(2,2′-Bipyridine)bis(N-methyl-4,4′-bi-pyridinium)platinum(II) tetraperchlorate

Ken Sakai, Manabu Osada, Yoshimi Yokoyama, Yasushi Tomita, Taro Tsubomura

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

In the title compound, [Pt(C10H8N2)(C 11H11N2)2](ClO4) 4, the square-planar PtN4 coordination geometry is slightly deformed, with the coordinated N atom of one of the N-methyl-4,4′-bipyridinium (MQ) ligands 0.262 (8) Å out of the plane defined by the rest of the coordinated N atoms and the Pt atom. The exceptional behavior of this MQ ligand is interpreted in terms of the electrostatic interactions between the positively charged MQ ligands and the perchlorate anions, where the N(MQ)⋯O(perchlorate) distances are in the range 2.932 (12)-3.259 (13) Å.

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume59
Issue number7
DOIs
Publication statusPublished - Jul 1 2003

Fingerprint

Platinum
platinum
Ligands
perchlorates
Atoms
ligands
atoms
Coulomb interactions
Static Electricity
Anions
Negative ions
electrostatics
anions
Geometry
geometry
perchlorate
interactions

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

(2,2′-Bipyridine)bis(N-methyl-4,4′-bi-pyridinium)platinum(II) tetraperchlorate. / Sakai, Ken; Osada, Manabu; Yokoyama, Yoshimi; Tomita, Yasushi; Tsubomura, Taro.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 59, No. 7, 01.07.2003.

Research output: Contribution to journalArticle

Sakai, Ken ; Osada, Manabu ; Yokoyama, Yoshimi ; Tomita, Yasushi ; Tsubomura, Taro. / (2,2′-Bipyridine)bis(N-methyl-4,4′-bi-pyridinium)platinum(II) tetraperchlorate. In: Acta Crystallographica Section E: Structure Reports Online. 2003 ; Vol. 59, No. 7.
@article{09238c53697f4736b0aab24a95a4b2b4,
title = "(2,2′-Bipyridine)bis(N-methyl-4,4′-bi-pyridinium)platinum(II) tetraperchlorate",
abstract = "In the title compound, [Pt(C10H8N2)(C 11H11N2)2](ClO4) 4, the square-planar PtN4 coordination geometry is slightly deformed, with the coordinated N atom of one of the N-methyl-4,4′-bipyridinium (MQ) ligands 0.262 (8) {\AA} out of the plane defined by the rest of the coordinated N atoms and the Pt atom. The exceptional behavior of this MQ ligand is interpreted in terms of the electrostatic interactions between the positively charged MQ ligands and the perchlorate anions, where the N(MQ)⋯O(perchlorate) distances are in the range 2.932 (12)-3.259 (13) {\AA}.",
author = "Ken Sakai and Manabu Osada and Yoshimi Yokoyama and Yasushi Tomita and Taro Tsubomura",
year = "2003",
month = "7",
day = "1",
doi = "10.1107/S1600536803013801",
language = "English",
volume = "59",
journal = "Acta Crystallographica Section E: Structure Reports Online",
issn = "1600-5368",
publisher = "International Union of Crystallography",
number = "7",

}

TY - JOUR

T1 - (2,2′-Bipyridine)bis(N-methyl-4,4′-bi-pyridinium)platinum(II) tetraperchlorate

AU - Sakai, Ken

AU - Osada, Manabu

AU - Yokoyama, Yoshimi

AU - Tomita, Yasushi

AU - Tsubomura, Taro

PY - 2003/7/1

Y1 - 2003/7/1

N2 - In the title compound, [Pt(C10H8N2)(C 11H11N2)2](ClO4) 4, the square-planar PtN4 coordination geometry is slightly deformed, with the coordinated N atom of one of the N-methyl-4,4′-bipyridinium (MQ) ligands 0.262 (8) Å out of the plane defined by the rest of the coordinated N atoms and the Pt atom. The exceptional behavior of this MQ ligand is interpreted in terms of the electrostatic interactions between the positively charged MQ ligands and the perchlorate anions, where the N(MQ)⋯O(perchlorate) distances are in the range 2.932 (12)-3.259 (13) Å.

AB - In the title compound, [Pt(C10H8N2)(C 11H11N2)2](ClO4) 4, the square-planar PtN4 coordination geometry is slightly deformed, with the coordinated N atom of one of the N-methyl-4,4′-bipyridinium (MQ) ligands 0.262 (8) Å out of the plane defined by the rest of the coordinated N atoms and the Pt atom. The exceptional behavior of this MQ ligand is interpreted in terms of the electrostatic interactions between the positively charged MQ ligands and the perchlorate anions, where the N(MQ)⋯O(perchlorate) distances are in the range 2.932 (12)-3.259 (13) Å.

UR - http://www.scopus.com/inward/record.url?scp=18444410267&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=18444410267&partnerID=8YFLogxK

U2 - 10.1107/S1600536803013801

DO - 10.1107/S1600536803013801

M3 - Article

AN - SCOPUS:18444410267

VL - 59

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

SN - 1600-5368

IS - 7

ER -