(2,2′-Bipyridine)chloro(4′-tolyl-2,2′:6′, 2″-terpyridine)iridium(III) bis(hexafluorophosphate) acetonitrile disolvate

Tomona Yutaka, Shinya Obara, Masa Aki Haga, Yoshimi Yokoyama, Ken Sakai

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

In the title compound, [IrCl(C10H8N 2)(C22H17N3)]-(PF6) 2·2C2H3N, the complex cation [Ir IIICl(bpy)(tterpyj]2- shows a deformed octahedral coordination geometry (tterpy = 4′-tolyl-2,2′:6′,2″- terpyridine and bpy = 2,2′-bipyridine). Due to the relatively strong intercationic tterpy-tterpy associations, the tolyl group deviates significantly from ideal geometry. The benzene ring of tterpy is inclined with respect to the central pyridyl ring at an angle of 24.7 (1)°.

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume61
Issue number7
DOIs
Publication statusPublished - Jul 1 2005

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Iridium
iridium
Acetonitrile
acetonitrile
Geometry
rings
geometry
Benzene
Cations
Positive ions
benzene
cations

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

(2,2′-Bipyridine)chloro(4′-tolyl-2,2′:6′, 2″-terpyridine)iridium(III) bis(hexafluorophosphate) acetonitrile disolvate. / Yutaka, Tomona; Obara, Shinya; Haga, Masa Aki; Yokoyama, Yoshimi; Sakai, Ken.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 61, No. 7, 01.07.2005.

Research output: Contribution to journalArticle

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abstract = "In the title compound, [IrCl(C10H8N 2)(C22H17N3)]-(PF6) 2·2C2H3N, the complex cation [Ir IIICl(bpy)(tterpyj]2- shows a deformed octahedral coordination geometry (tterpy = 4′-tolyl-2,2′:6′,2″- terpyridine and bpy = 2,2′-bipyridine). Due to the relatively strong intercationic tterpy-tterpy associations, the tolyl group deviates significantly from ideal geometry. The benzene ring of tterpy is inclined with respect to the central pyridyl ring at an angle of 24.7 (1)°.",
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T1 - (2,2′-Bipyridine)chloro(4′-tolyl-2,2′:6′, 2″-terpyridine)iridium(III) bis(hexafluorophosphate) acetonitrile disolvate

AU - Yutaka, Tomona

AU - Obara, Shinya

AU - Haga, Masa Aki

AU - Yokoyama, Yoshimi

AU - Sakai, Ken

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N2 - In the title compound, [IrCl(C10H8N 2)(C22H17N3)]-(PF6) 2·2C2H3N, the complex cation [Ir IIICl(bpy)(tterpyj]2- shows a deformed octahedral coordination geometry (tterpy = 4′-tolyl-2,2′:6′,2″- terpyridine and bpy = 2,2′-bipyridine). Due to the relatively strong intercationic tterpy-tterpy associations, the tolyl group deviates significantly from ideal geometry. The benzene ring of tterpy is inclined with respect to the central pyridyl ring at an angle of 24.7 (1)°.

AB - In the title compound, [IrCl(C10H8N 2)(C22H17N3)]-(PF6) 2·2C2H3N, the complex cation [Ir IIICl(bpy)(tterpyj]2- shows a deformed octahedral coordination geometry (tterpy = 4′-tolyl-2,2′:6′,2″- terpyridine and bpy = 2,2′-bipyridine). Due to the relatively strong intercationic tterpy-tterpy associations, the tolyl group deviates significantly from ideal geometry. The benzene ring of tterpy is inclined with respect to the central pyridyl ring at an angle of 24.7 (1)°.

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