(2,2′-Bipyridine)chloro(4′-tolyl-2,2′:6′, 2″-terpyridine)iridium(III) bis(hexafluorophosphate) acetonitrile disolvate

Tomona Yutaka, Shinya Obara, Masa Aki Haga, Yoshimi Yokoyama, Ken Sakai

Research output: Contribution to journalArticlepeer-review

6 Citations (Scopus)

Abstract

In the title compound, [IrCl(C10H8N 2)(C22H17N3)]-(PF6) 2·2C2H3N, the complex cation [Ir IIICl(bpy)(tterpyj]2- shows a deformed octahedral coordination geometry (tterpy = 4′-tolyl-2,2′:6′,2″- terpyridine and bpy = 2,2′-bipyridine). Due to the relatively strong intercationic tterpy-tterpy associations, the tolyl group deviates significantly from ideal geometry. The benzene ring of tterpy is inclined with respect to the central pyridyl ring at an angle of 24.7 (1)°.

Original languageEnglish
Pages (from-to)m1357-m1359
JournalActa Crystallographica Section E: Structure Reports Online
Volume61
Issue number7
DOIs
Publication statusPublished - Jul 1 2005

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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