Abstract
2,6-Disubstituted-3,5-dimethylpyrazines have been synthesized via biased acetal synthesis from symmetric 2,3,5,6-tetrakis(chloromethyl)pyrazine. The pyrazine ligands coordinated to trans-dichloropalladium(II) at the nitrogen whose neighboring carbons were connected to less hindered methyl groups. 2,6-Bis(porphyrin)-substituted pyrazine bound C60 to yield 1:1 inclusion complex. The binding of C60 with the pyrazine ligand and its zinc complex was determined by ESI-MS, NMR, and fluorescence spectroscopic analyses.
| Original language | English |
|---|---|
| Pages (from-to) | 282-288 |
| Number of pages | 7 |
| Journal | Tetrahedron |
| Volume | 65 |
| Issue number | 1 |
| DOIs | |
| Publication status | Published - Jan 3 2009 |
All Science Journal Classification (ASJC) codes
- Biochemistry
- Drug Discovery
- Organic Chemistry
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Eda, Y., Itoh, K., Ito, Y., & Kawato, T. (2009). 2,6-Bis(porphyrin)-substituted pyrazine: a new class of supramolecular synthon binding to a transition-metal ion and fullerene (C60). Tetrahedron, 65(1), 282-288. https://doi.org/10.1016/j.tet.2008.10.057