@article{11f1a78021df4ae180e6ea8b9af0ea91,
title = "3-Azidoarynes: Generation and Regioselective Reactions",
abstract = "The generation of 3-azidoarynes from o-iodoaryl triflatetype precursors was achieved using a silylmethyl Grignard reagent as the activator. The azido group served to control the regioselectivity of the reaction of 3-azidoarynes with arynophiles. The remaining azido group in the adduct also served as a transformable functional group, enabling further derivatization to various nitrogen-containing compounds. ",
author = "Jumpei Taguchi and Kota Kimura and Kazunobu Igawa and Katsuhiko Tomooka and Takamitsu Hosoya",
note = "Funding Information: This work was supported by the Japan Agency for Medical Research and Development (AMED) under Grant Numbers JP21am0101098 (Platform Project for Supporting Drug Discovery and Life Science Research, BINDS) and JP21gm0910007 (CREST); JSPS KAKENHI Grant Numbers JP18H02104 (B; T.H.), JP18H04386 (Middle Molecular Strategy; T.H.), and JP17H06414 (Organelle Zone; T.H.); the Cooperative Research Project of Research Center for Biomedical Engineering; and the Research Program of “Five-Star Alliance” in “NJRC Mater. & Dev.”. Publisher Copyright: {\textcopyright} 2022 The Chemical Society of Japan.",
year = "2022",
month = feb,
doi = "10.1246/cl.210632",
language = "English",
volume = "51",
pages = "94--98",
journal = "Chemistry Letters",
issn = "0366-7022",
publisher = "The Chemical Society of Japan",
number = "2",
}