(4-Amino-2,2′-bipyridine)dichloroplatinum(II) dihydrate

Ken Sakai, Yoshimi Yokoyama, Ken Okamoto, Satoru Takahashi

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

In the crystal structure of the title compound, [PtCl2(C 10H9N3)]·2H2O, the square-planar platinum complexes form one-dimensional columns based on the π-π-stacking interactions between the 4-amino-2,2′-bipyridine ligands, where the plane-to-plane separations are 3.45 (1) and 3.47 (1) Å. The Pt⋯Pt distances in the column are 5.1214 (7) and 6.1648 (7) Å, suggesting no metal-metal interaction. Intermolecular hydrogen bonds are formed among the water molecules, the amino groups, and the coordinated Cl atoms.

Original languageEnglish
Pages (from-to)m518-m520
JournalActa Crystallographica Section E: Structure Reports Online
Volume59
Issue number7
DOIs
Publication statusPublished - Jul 1 2003
Externally publishedYes

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Metals
Platinum
metals
Hydrogen bonds
platinum
Crystal structure
Ligands
interactions
hydrogen bonds
Atoms
ligands
crystal structure
Molecules
Water
water
atoms
molecules

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

(4-Amino-2,2′-bipyridine)dichloroplatinum(II) dihydrate. / Sakai, Ken; Yokoyama, Yoshimi; Okamoto, Ken; Takahashi, Satoru.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 59, No. 7, 01.07.2003, p. m518-m520.

Research output: Contribution to journalArticle

Sakai, Ken ; Yokoyama, Yoshimi ; Okamoto, Ken ; Takahashi, Satoru. / (4-Amino-2,2′-bipyridine)dichloroplatinum(II) dihydrate. In: Acta Crystallographica Section E: Structure Reports Online. 2003 ; Vol. 59, No. 7. pp. m518-m520.
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