4,5-bis(diarylmethylene)-1,3-dithiole

A novel helical electron donor exhibiting electrochromic behavior

Takanori Suzuki, Shintaro Mikum, Yusuke Ishigaki, Hiroki Higuchi, Hidetoshi Kawai, Kenshu Fujiwara

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

Vivid color change from intense yellow to deep purple was observed upon electrochemcal oxidation of the title donor 1 to bis(Michler's hydrol blue)-type dication 1 2+ . Since the interconversion was also accompanied by drastic geometric changes, configurational stability of the helical π-arrangement is modified upon redox reactions.

Original languageEnglish
Pages (from-to)748-749
Number of pages2
JournalChemistry Letters
Volume38
Issue number7
DOIs
Publication statusPublished - Jul 20 2009

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Redox reactions
Color
Oxidation
Electrons
Michler's hydrol blue

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

Cite this

Suzuki, T., Mikum, S., Ishigaki, Y., Higuchi, H., Kawai, H., & Fujiwara, K. (2009). 4,5-bis(diarylmethylene)-1,3-dithiole: A novel helical electron donor exhibiting electrochromic behavior. Chemistry Letters, 38(7), 748-749. https://doi.org/10.1246/cl.2009.748

4,5-bis(diarylmethylene)-1,3-dithiole : A novel helical electron donor exhibiting electrochromic behavior. / Suzuki, Takanori; Mikum, Shintaro; Ishigaki, Yusuke; Higuchi, Hiroki; Kawai, Hidetoshi; Fujiwara, Kenshu.

In: Chemistry Letters, Vol. 38, No. 7, 20.07.2009, p. 748-749.

Research output: Contribution to journalArticle

Suzuki, T, Mikum, S, Ishigaki, Y, Higuchi, H, Kawai, H & Fujiwara, K 2009, '4,5-bis(diarylmethylene)-1,3-dithiole: A novel helical electron donor exhibiting electrochromic behavior', Chemistry Letters, vol. 38, no. 7, pp. 748-749. https://doi.org/10.1246/cl.2009.748
Suzuki, Takanori ; Mikum, Shintaro ; Ishigaki, Yusuke ; Higuchi, Hiroki ; Kawai, Hidetoshi ; Fujiwara, Kenshu. / 4,5-bis(diarylmethylene)-1,3-dithiole : A novel helical electron donor exhibiting electrochromic behavior. In: Chemistry Letters. 2009 ; Vol. 38, No. 7. pp. 748-749.
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