4,5-Bis(diarylmethylene)-1,3-dithiole: A Novel Helical Electron Donor Exhibiting Electrochromic Behavior

Takanori Suzuki, Shintaro Mikuni, Yusuke Ishigaki, Hiroki Higuchi, Hidetoshi Kawai, Kenshu Fujiwara

Research output: Contribution to journalArticlepeer-review

Abstract

Vivid color change from intense yellow to deep purple was observed upon electrochemcal oxidation of the title donor <B>1</B> to bis(Michler's hydrol blue)-type dication <B>1</B><SUP>2+</SUP>. Since the interconversion was also accompanied by drastic geometric changes, configurational stability of the helical π-arrangement is modified upon redox reactions.
Original languageEnglish
Pages (from-to)748-749
Number of pages2
JournalChemistry Letters
Volume38
Issue number7
DOIs
Publication statusPublished - Jul 5 2009

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