(5R*)-5-[(2S*5S*)-1-Methoxy-5-phenylpyrrolidin-2-yl] -3-methylfuran-2(5H)-one

Takeshi Oishi, Makoto Yoritate, Takaaki Sato, Noritaka Chida

Research output: Contribution to journalArticle

Abstract

In the title compound, C16H19NO3, the pyrrolidine ring is in a twist conformation. The dihedral angle between the dihydrofuran ring [maximum deviation = 0.0016(11)Å] and the phenyl ring is 47.22(8)°. In the crystal, molecules are linked by weak C - H⋯O hydrogen bonds, forming helical chains along the b-axis direction. The chains are further linked by C - H⋯π interactions to constitute a three-dimensional architecture.

Original languageEnglish
Pages (from-to)o839
JournalActa Crystallographica Section E: Structure Reports Online
Volume70
Issue number8
DOIs
Publication statusPublished - Aug 2014

Fingerprint

Dihedral angle
Conformations
Hydrogen bonds
Crystals
Molecules
rings
dihedral angle
hydrogen bonds
deviation
crystals
Direction compound
3-methylfuran
pyrrolidine
molecules
interactions

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

(5R*)-5-[(2S*5S*)-1-Methoxy-5-phenylpyrrolidin-2-yl] -3-methylfuran-2(5H)-one. / Oishi, Takeshi; Yoritate, Makoto; Sato, Takaaki; Chida, Noritaka.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 70, No. 8, 08.2014, p. o839.

Research output: Contribution to journalArticle

@article{efae7498c5b34224acb89a180320e2ee,
title = "(5R*)-5-[(2S*5S*)-1-Methoxy-5-phenylpyrrolidin-2-yl] -3-methylfuran-2(5H)-one",
abstract = "In the title compound, C16H19NO3, the pyrrolidine ring is in a twist conformation. The dihedral angle between the dihydrofuran ring [maximum deviation = 0.0016(11){\AA}] and the phenyl ring is 47.22(8)°. In the crystal, molecules are linked by weak C - H⋯O hydrogen bonds, forming helical chains along the b-axis direction. The chains are further linked by C - H⋯π interactions to constitute a three-dimensional architecture.",
author = "Takeshi Oishi and Makoto Yoritate and Takaaki Sato and Noritaka Chida",
year = "2014",
month = "8",
doi = "10.1107/S1600536814014974",
language = "English",
volume = "70",
pages = "o839",
journal = "Acta Crystallographica Section E: Structure Reports Online",
issn = "1600-5368",
publisher = "International Union of Crystallography",
number = "8",

}

TY - JOUR

T1 - (5R*)-5-[(2S*5S*)-1-Methoxy-5-phenylpyrrolidin-2-yl] -3-methylfuran-2(5H)-one

AU - Oishi, Takeshi

AU - Yoritate, Makoto

AU - Sato, Takaaki

AU - Chida, Noritaka

PY - 2014/8

Y1 - 2014/8

N2 - In the title compound, C16H19NO3, the pyrrolidine ring is in a twist conformation. The dihedral angle between the dihydrofuran ring [maximum deviation = 0.0016(11)Å] and the phenyl ring is 47.22(8)°. In the crystal, molecules are linked by weak C - H⋯O hydrogen bonds, forming helical chains along the b-axis direction. The chains are further linked by C - H⋯π interactions to constitute a three-dimensional architecture.

AB - In the title compound, C16H19NO3, the pyrrolidine ring is in a twist conformation. The dihedral angle between the dihydrofuran ring [maximum deviation = 0.0016(11)Å] and the phenyl ring is 47.22(8)°. In the crystal, molecules are linked by weak C - H⋯O hydrogen bonds, forming helical chains along the b-axis direction. The chains are further linked by C - H⋯π interactions to constitute a three-dimensional architecture.

UR - http://www.scopus.com/inward/record.url?scp=84905505821&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84905505821&partnerID=8YFLogxK

U2 - 10.1107/S1600536814014974

DO - 10.1107/S1600536814014974

M3 - Article

AN - SCOPUS:84905505821

VL - 70

SP - o839

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

SN - 1600-5368

IS - 8

ER -