[60]fullerene can reinforce the organogel structure of porphyrin-appended cholesterol derivatives: Novel odd-even effect of the (CH2)n spacer on the organogel stability

Tsutomu Ishi- i; Ritsuko Iguchi; Erwin Snip; Masato Ikeda; Seiji Shinkai

doi:10.1021/la0107749

[60]fullerene can reinforce the organogel structure of porphyrin-appended cholesterol derivatives: Novel odd-even effect of the (CH₂)_n spacer on the organogel stability

Tsutomu Ishi- i, Ritsuko Iguchi, Erwin Snip, Masato Ikeda, Seiji Shinkai

Institute for Advanced Study

Research output: Contribution to journal › Article › peer-review

131 Citations (Scopus)

Abstract

The influence of added [60]fullerene on the gelation ability of Zn(II) porphyrin appended cholestrol derivatives was discussed. A highly ordered aggregation mode was induced by the intermolecular Zn(II) porphyrin-[60]fullerene interaction that forced porphyrin moieties to form regular sandwich complexes with [60]fullerene. The analysis showed that the slight structural charge in gelators was multiplicatively reflected by the higher order structure of the organogel fibers.

Original language	English
Pages (from-to)	5825-5833
Number of pages	9
Journal	Langmuir
Volume	17
Issue number	19
DOIs	https://doi.org/10.1021/la0107749
Publication status	Published - Sept 18 2001

All Science Journal Classification (ASJC) codes

Materials Science(all)
Condensed Matter Physics
Surfaces and Interfaces
Spectroscopy
Electrochemistry

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10.1021/la0107749

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abstract = "The influence of added [60]fullerene on the gelation ability of Zn(II) porphyrin appended cholestrol derivatives was discussed. A highly ordered aggregation mode was induced by the intermolecular Zn(II) porphyrin-[60]fullerene interaction that forced porphyrin moieties to form regular sandwich complexes with [60]fullerene. The analysis showed that the slight structural charge in gelators was multiplicatively reflected by the higher order structure of the organogel fibers.",

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T2 - Novel odd-even effect of the (CH2)n spacer on the organogel stability

AU - Ishi- i, Tsutomu

AU - Iguchi, Ritsuko

AU - Snip, Erwin

AU - Ikeda, Masato

AU - Shinkai, Seiji

PY - 2001/9/18

Y1 - 2001/9/18

N2 - The influence of added [60]fullerene on the gelation ability of Zn(II) porphyrin appended cholestrol derivatives was discussed. A highly ordered aggregation mode was induced by the intermolecular Zn(II) porphyrin-[60]fullerene interaction that forced porphyrin moieties to form regular sandwich complexes with [60]fullerene. The analysis showed that the slight structural charge in gelators was multiplicatively reflected by the higher order structure of the organogel fibers.

AB - The influence of added [60]fullerene on the gelation ability of Zn(II) porphyrin appended cholestrol derivatives was discussed. A highly ordered aggregation mode was induced by the intermolecular Zn(II) porphyrin-[60]fullerene interaction that forced porphyrin moieties to form regular sandwich complexes with [60]fullerene. The analysis showed that the slight structural charge in gelators was multiplicatively reflected by the higher order structure of the organogel fibers.

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ER -

[60]fullerene can reinforce the organogel structure of porphyrin-appended cholesterol derivatives: Novel odd-even effect of the (CH₂)_n spacer on the organogel stability

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