9,9′-Anthryl-anthroxyl radicals: Strategic stabilization of highly reactive phenoxyl radicals

Tatsuya Aotake; Mitsuharu Suzuki; Naoki Aratani; Junpei Yuasa; Daiki Kuzuhara; Hironobu Hayashi; Haruyuki Nakano; Tsuyoshi Kawai; Jishan Wu; Hiroko Yamada

doi:10.1039/c4cc10104a

9,9′-Anthryl-anthroxyl radicals: Strategic stabilization of highly reactive phenoxyl radicals

Tatsuya Aotake, Mitsuharu Suzuki, Naoki Aratani, Junpei Yuasa, Daiki Kuzuhara, Hironobu Hayashi, Haruyuki Nakano, Tsuyoshi Kawai, Jishan Wu, Hiroko Yamada

Multidisciplinary chemistry

Research output: Contribution to journal › Article

10 Citations (Scopus)

Abstract

Stable 9,9′-anthryl-anthroxyl radicals were synthesized and isolated, and the structures were fully characterized by single crystal X-ray diffraction analysis and ESR measurement. The resonance structure and steric protection of the peripheral positions and the most reactive 9-position of anthracene prolong the half-life of the radical in solution to 11 days. This journal is

Original language	English
Pages (from-to)	6734-6737
Number of pages	4
Journal	Chemical Communications
Volume	51
Issue number	31
DOIs	https://doi.org/10.1039/c4cc10104a
Publication status	Published - Apr 21 2015

Fingerprint

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Cite this

Aotake, T., Suzuki, M., Aratani, N., Yuasa, J., Kuzuhara, D., Hayashi, H., ... Yamada, H. (2015). 9,9′-Anthryl-anthroxyl radicals: Strategic stabilization of highly reactive phenoxyl radicals. Chemical Communications, 51(31), 6734-6737. https://doi.org/10.1039/c4cc10104a

9,9′-Anthryl-anthroxyl radicals : Strategic stabilization of highly reactive phenoxyl radicals. / Aotake, Tatsuya; Suzuki, Mitsuharu; Aratani, Naoki; Yuasa, Junpei; Kuzuhara, Daiki; Hayashi, Hironobu; Nakano, Haruyuki; Kawai, Tsuyoshi; Wu, Jishan; Yamada, Hiroko.

In: Chemical Communications, Vol. 51, No. 31, 21.04.2015, p. 6734-6737.

Research output: Contribution to journal › Article

@article{abdf4c29a2ac4e1c8be672f8230a3b58,

title = "9,9′-Anthryl-anthroxyl radicals: Strategic stabilization of highly reactive phenoxyl radicals",

abstract = "Stable 9,9′-anthryl-anthroxyl radicals were synthesized and isolated, and the structures were fully characterized by single crystal X-ray diffraction analysis and ESR measurement. The resonance structure and steric protection of the peripheral positions and the most reactive 9-position of anthracene prolong the half-life of the radical in solution to 11 days. This journal is",

author = "Tatsuya Aotake and Mitsuharu Suzuki and Naoki Aratani and Junpei Yuasa and Daiki Kuzuhara and Hironobu Hayashi and Haruyuki Nakano and Tsuyoshi Kawai and Jishan Wu and Hiroko Yamada",

year = "2015",

month = "4",

day = "21",

doi = "10.1039/c4cc10104a",

language = "English",

volume = "51",

pages = "6734--6737",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "31",

}

TY - JOUR

T1 - 9,9′-Anthryl-anthroxyl radicals

T2 - Strategic stabilization of highly reactive phenoxyl radicals

AU - Aotake, Tatsuya

AU - Suzuki, Mitsuharu

AU - Aratani, Naoki

AU - Yuasa, Junpei

AU - Kuzuhara, Daiki

AU - Hayashi, Hironobu

AU - Nakano, Haruyuki

AU - Kawai, Tsuyoshi

AU - Wu, Jishan

AU - Yamada, Hiroko

PY - 2015/4/21

Y1 - 2015/4/21

N2 - Stable 9,9′-anthryl-anthroxyl radicals were synthesized and isolated, and the structures were fully characterized by single crystal X-ray diffraction analysis and ESR measurement. The resonance structure and steric protection of the peripheral positions and the most reactive 9-position of anthracene prolong the half-life of the radical in solution to 11 days. This journal is

AB - Stable 9,9′-anthryl-anthroxyl radicals were synthesized and isolated, and the structures were fully characterized by single crystal X-ray diffraction analysis and ESR measurement. The resonance structure and steric protection of the peripheral positions and the most reactive 9-position of anthracene prolong the half-life of the radical in solution to 11 days. This journal is

UR - http://www.scopus.com/inward/record.url?scp=84926663232&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84926663232&partnerID=8YFLogxK

U2 - 10.1039/c4cc10104a

DO - 10.1039/c4cc10104a

M3 - Article

C2 - 25679354

AN - SCOPUS:84926663232

VL - 51

SP - 6734

EP - 6737

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 31

ER -

Access to Document

10.1039/c4cc10104a