9,9′-Anthryl-anthroxyl radicals: Strategic stabilization of highly reactive phenoxyl radicals

Tatsuya Aotake, Mitsuharu Suzuki, Naoki Aratani, Junpei Yuasa, Daiki Kuzuhara, Hironobu Hayashi, Haruyuki Nakano, Tsuyoshi Kawai, Jishan Wu, Hiroko Yamada

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

Stable 9,9′-anthryl-anthroxyl radicals were synthesized and isolated, and the structures were fully characterized by single crystal X-ray diffraction analysis and ESR measurement. The resonance structure and steric protection of the peripheral positions and the most reactive 9-position of anthracene prolong the half-life of the radical in solution to 11 days. This journal is

Original languageEnglish
Pages (from-to)6734-6737
Number of pages4
JournalChemical Communications
Volume51
Issue number31
DOIs
Publication statusPublished - Apr 21 2015

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Stabilization
Anthracene
X ray diffraction analysis
Paramagnetic resonance
Single crystals
phenoxy radical
anthracene

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Cite this

Aotake, T., Suzuki, M., Aratani, N., Yuasa, J., Kuzuhara, D., Hayashi, H., ... Yamada, H. (2015). 9,9′-Anthryl-anthroxyl radicals: Strategic stabilization of highly reactive phenoxyl radicals. Chemical Communications, 51(31), 6734-6737. https://doi.org/10.1039/c4cc10104a

9,9′-Anthryl-anthroxyl radicals : Strategic stabilization of highly reactive phenoxyl radicals. / Aotake, Tatsuya; Suzuki, Mitsuharu; Aratani, Naoki; Yuasa, Junpei; Kuzuhara, Daiki; Hayashi, Hironobu; Nakano, Haruyuki; Kawai, Tsuyoshi; Wu, Jishan; Yamada, Hiroko.

In: Chemical Communications, Vol. 51, No. 31, 21.04.2015, p. 6734-6737.

Research output: Contribution to journalArticle

Aotake, T, Suzuki, M, Aratani, N, Yuasa, J, Kuzuhara, D, Hayashi, H, Nakano, H, Kawai, T, Wu, J & Yamada, H 2015, '9,9′-Anthryl-anthroxyl radicals: Strategic stabilization of highly reactive phenoxyl radicals', Chemical Communications, vol. 51, no. 31, pp. 6734-6737. https://doi.org/10.1039/c4cc10104a
Aotake T, Suzuki M, Aratani N, Yuasa J, Kuzuhara D, Hayashi H et al. 9,9′-Anthryl-anthroxyl radicals: Strategic stabilization of highly reactive phenoxyl radicals. Chemical Communications. 2015 Apr 21;51(31):6734-6737. https://doi.org/10.1039/c4cc10104a
Aotake, Tatsuya ; Suzuki, Mitsuharu ; Aratani, Naoki ; Yuasa, Junpei ; Kuzuhara, Daiki ; Hayashi, Hironobu ; Nakano, Haruyuki ; Kawai, Tsuyoshi ; Wu, Jishan ; Yamada, Hiroko. / 9,9′-Anthryl-anthroxyl radicals : Strategic stabilization of highly reactive phenoxyl radicals. In: Chemical Communications. 2015 ; Vol. 51, No. 31. pp. 6734-6737.
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