A Bis-[C(trimethylsilyl)-N-arylimino]dimethylsilane, Me 3Si(C= NAr)SiMe 2(C=NAr)SiMe 3 (Ar = 2,6-xylyl), as a New β-Diimine Ligand

Masao Tanabiki, Yusuke Sunada, Hideo Nagashima

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

A cobalt complex having bis-[C(trimethylsilyl)-N-arylimino]dimethylsilane, Me 3Si(C=NAr)SiMe 2(C=NAr)SiMe 3 (Ar = 2,6-xylyl), as a new β-diimine ligand was synthesized, and its structure was compared with those of α- and β-diimine cobalt complexes. Ethylene polymerization catalyzed by these cobalt complexes and their in situ generated nickel homologues was investigated.

Original languageEnglish
Pages (from-to)6055-6058
Number of pages4
JournalOrganometallics
Volume26
Issue number24
DOIs
Publication statusPublished - Nov 19 2007

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Cobalt
cobalt
Ligands
ligands
Nickel
ethylene
polymerization
Polymerization
nickel

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

Cite this

A Bis-[C(trimethylsilyl)-N-arylimino]dimethylsilane, Me 3Si(C= NAr)SiMe 2(C=NAr)SiMe 3 (Ar = 2,6-xylyl), as a New β-Diimine Ligand. / Tanabiki, Masao; Sunada, Yusuke; Nagashima, Hideo.

In: Organometallics, Vol. 26, No. 24, 19.11.2007, p. 6055-6058.

Research output: Contribution to journalArticle

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