A bistable porous coordination polymer with a bond-switching mechanism showing reversible structural and functional transformations

Sujit K. Ghosh, Wakako Kaneko, Daisuke Kiriya, Masaaki Ohba, Susumu Kitagawa

Research output: Contribution to journalArticle

163 Citations (Scopus)

Abstract

Ring the changes: A 2D crystalline coordination polymer 1 is transformed reversibly into a 3D crystal 1a by dehydration. This reversible structural transformation is accompanied by a change in optical and magnetic properties. The 3D coordination framework absorbs H2O molecules but rejects common organic solvents, such as MeOH, EtOH, THF, and Me2CO. (Figure Presented)

Original languageEnglish
Pages (from-to)8843-8847
Number of pages5
JournalAngewandte Chemie - International Edition
Volume47
Issue number46
DOIs
Publication statusPublished - Nov 3 2008
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

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