A bistable porous coordination polymer with a bond-switching mechanism showing reversible structural and functional transformations

Sujit K. Ghosh, Wakako Kaneko, Daisuke Kiriya, Masaaki Ohba, Susumu Kitagawa

Research output: Contribution to journalArticle

161 Citations (Scopus)

Abstract

Ring the changes: A 2D crystalline coordination polymer 1 is transformed reversibly into a 3D crystal 1a by dehydration. This reversible structural transformation is accompanied by a change in optical and magnetic properties. The 3D coordination framework absorbs H2O molecules but rejects common organic solvents, such as MeOH, EtOH, THF, and Me2CO. (Figure Presented)

Original languageEnglish
Pages (from-to)8843-8847
Number of pages5
JournalAngewandte Chemie - International Edition
Volume47
Issue number46
DOIs
Publication statusPublished - Nov 3 2008
Externally publishedYes

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Dehydration
Organic solvents
Magnetic properties
Polymers
Optical properties
Crystalline materials
Crystals
Molecules

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

Cite this

A bistable porous coordination polymer with a bond-switching mechanism showing reversible structural and functional transformations. / Ghosh, Sujit K.; Kaneko, Wakako; Kiriya, Daisuke; Ohba, Masaaki; Kitagawa, Susumu.

In: Angewandte Chemie - International Edition, Vol. 47, No. 46, 03.11.2008, p. 8843-8847.

Research output: Contribution to journalArticle

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