A cationic diruthenium amidinate, [(η5-C5Me 5)Ru(μ2-i-PrN=C(Me)Ni-Pr)Ru(η5-C 5Me5)]+, as an efficient catalyst for the atom-transfer radical reactions

Yukihiro Motoyama, Mitsuru Gondo, Satoshi Masuda, Yuya Iwashita, Hideo Nagashima

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25 Citations (Scopus)

Abstract

A cationic diruthenium amidinate, [(η5-C5Me 5)Ru(μ2-i-PrN=C(Me)Ni-Pr)Ru(η5-C 5Me5)]+, is generated by treatment of (η5-C5Me5)Ru(μ2-i-PrN=C(Me) Ni-Pr)Ru(Cl)(η5-C5Me5) (3a) with NaPF 6 or other metal salts of weakly coordinating anions, which is active towards catalytic atom transfer radical cyclization of N-allyl trichloroacetamides and related reactions.

Original languageEnglish
Pages (from-to)442-443
Number of pages2
JournalChemistry Letters
Volume33
Issue number4
DOIs
Publication statusPublished - Apr 5 2004

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Cyclization
Anions
Salts
Metals
Atoms
Catalysts
trichloroacetamide

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

Cite this

A cationic diruthenium amidinate, [(η5-C5Me 5)Ru(μ2-i-PrN=C(Me)Ni-Pr)Ru(η5-C 5Me5)]+, as an efficient catalyst for the atom-transfer radical reactions. / Motoyama, Yukihiro; Gondo, Mitsuru; Masuda, Satoshi; Iwashita, Yuya; Nagashima, Hideo.

In: Chemistry Letters, Vol. 33, No. 4, 05.04.2004, p. 442-443.

Research output: Contribution to journalArticle

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AU - Nagashima, Hideo

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