A macrocyclic N-heterocyclic carbene (NHC)–cobalt complex was found to act as an improved H2-evolving catalyst in a [Ru(bpy)3]2+-sensitized photosystem using methylviologen as a redox acceptor (MV2++ e−→ MV+, MV2+= N N ′-dimethyl-4,4′-bipyridinium), which provides a driving force of only 150 meV for H2evolution at pH 5.0.
All Science Journal Classification (ASJC) codes
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- Surfaces, Coatings and Films
- Metals and Alloys
- Materials Chemistry