Une étude complète visant à mesurer l'absorption absolue de dioxyde de carbone sur un adsorbant composite

Translated title of the contribution: A comprehensive study to evaluate absolute uptake of carbon dioxide adsorption onto composite adsorbent

Bakytnur Berdenova, Animesh Pal, Mahbubul Muttakin, Sourav Mitra, Thu Kyaw, Bidyut Baran Saha, Aidarkhan Kaltayev

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

In this study, new composite adsorbent with enhanced thermal conductivity and adsorption capacity was synthesized and analyzed comprehensively for the development of compact CO 2 based adsorption cooling system. The consolidated composite was prepared employing activated carbon, graphene nanoplatelets and hydroxyl cellulose as a parent adsorbent, thermal conductivity enhancer, and binder, respectively. The surface area and pore volume of the composite were found to be 1778 ± 13 m 2 g −1 and 1.014 cm 3 g −1 , respectively. In addition, the composite showed 233% higher thermal conductivity compared to the parent activated carbon. Adsorption characteristics of CO 2 were measured at temperature ranging from 20 to 70 °C and pressures up to 5 MPa. Absolute uptake was evaluated from excess adsorption based on the following two methods: (i) the adsorbed phase volume is equal to the pore volume of the adsorbent; and (ii) the adsorbed phase volume is almost zero under low pressure and/or high temperature conditions. Furthermore, the averaging of above two methods was also taken for avoiding these two extreme assumptions. Obtained absolute adsorption uptake data were fitted with modified Dubinin-Astakhov and Tóth models. Results indicated good approximation between data points and models. The average isosteric heats of adsorption estimated using modified D-A and Tóth model were found to be 19.742 kJ mol −1 and 19.023 kJ mol −1 , respectively. The obtained characteristics of composite adsorbent are prerequisites for designing compact CO 2 based adsorption cooling systems.

Original languageFrench
Pages (from-to)131-140
Number of pages10
JournalInternational Journal of Refrigeration
Volume100
DOIs
Publication statusPublished - Apr 1 2019

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Adsorbents
Carbon dioxide
Adsorption
Composite materials
Thermal conductivity
Cooling systems
Activated carbon
Graphene
Binders
Cellulose
Temperature

All Science Journal Classification (ASJC) codes

  • Building and Construction
  • Mechanical Engineering

Cite this

Une étude complète visant à mesurer l'absorption absolue de dioxyde de carbone sur un adsorbant composite. / Berdenova, Bakytnur; Pal, Animesh; Muttakin, Mahbubul; Mitra, Sourav; Kyaw, Thu; Saha, Bidyut Baran; Kaltayev, Aidarkhan.

In: International Journal of Refrigeration, Vol. 100, 01.04.2019, p. 131-140.

Research output: Contribution to journalArticle

Berdenova, Bakytnur ; Pal, Animesh ; Muttakin, Mahbubul ; Mitra, Sourav ; Kyaw, Thu ; Saha, Bidyut Baran ; Kaltayev, Aidarkhan. / Une étude complète visant à mesurer l'absorption absolue de dioxyde de carbone sur un adsorbant composite. In: International Journal of Refrigeration. 2019 ; Vol. 100. pp. 131-140.
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