A Convenient Route to Ruthenium(IV)-Allyl Complexes (C5Me5)RuX2(η3-allyl) from [(C5Me5)RuCl2]n

Hideo Nagashima; Katsunori Mukai; Yusuke Shiota; Ken Ichi Ara; Kenji Itoh; Hiroharu Suzuki; Noriaki Oshima; Yoshihiko Moro-oka

doi:10.1021/om00126a036

A Convenient Route to Ruthenium(IV)-Allyl Complexes (C₅Me₅)RuX₂(η³-allyl) from [(C₅Me₅)RuCl₂]n

Hideo Nagashima, Katsunori Mukai, Yusuke Shiota, Ken Ichi Ara, Kenji Itoh, Hiroharu Suzuki, Noriaki Oshima, Yoshihiko Moro-oka

Research output: Contribution to journal › Article › peer-review

37 Citations (Scopus)

Abstract

Ruthenium(IV)-allyl complexes (C₅Me₅)-RuCl₂(η³-allyl) are easily prepared from a Ru(III) complex, [(C₅Me₅)RuCl₂]_n, by treatment with allylic halides, alcohol, ethers, acetate, or sulfides. Treatment of the resulting dichlororuthenium(IV) complex with aqueous HBr or HI solution resulted in smooth halogen-exchange reactions.

Original language	English
Pages (from-to)	1314-1315
Number of pages	2
Journal	Organometallics
Volume	4
Issue number	7
DOIs	https://doi.org/10.1021/om00126a036
Publication status	Published - Jul 1985
Externally published	Yes

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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10.1021/om00126a036

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title = "A Convenient Route to Ruthenium(IV)-Allyl Complexes (C5Me5)RuX2(η3-allyl) from [(C5Me5)RuCl2]n",

abstract = "Ruthenium(IV)-allyl complexes (C5Me5)-RuCl2(η3-allyl) are easily prepared from a Ru(III) complex, [(C5Me5)RuCl2]n, by treatment with allylic halides, alcohol, ethers, acetate, or sulfides. Treatment of the resulting dichlororuthenium(IV) complex with aqueous HBr or HI solution resulted in smooth halogen-exchange reactions.",

author = "Hideo Nagashima and Katsunori Mukai and Yusuke Shiota and Ara, {Ken Ichi} and Kenji Itoh and Hiroharu Suzuki and Noriaki Oshima and Yoshihiko Moro-oka",

year = "1985",

month = jul,

doi = "10.1021/om00126a036",

language = "English",

volume = "4",

pages = "1314--1315",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

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T1 - A Convenient Route to Ruthenium(IV)-Allyl Complexes (C5Me5)RuX2(η3-allyl) from [(C5Me5)RuCl2]n

AU - Nagashima, Hideo

AU - Mukai, Katsunori

AU - Shiota, Yusuke

AU - Ara, Ken Ichi

AU - Itoh, Kenji

AU - Suzuki, Hiroharu

AU - Oshima, Noriaki

AU - Moro-oka, Yoshihiko

PY - 1985/7

Y1 - 1985/7

N2 - Ruthenium(IV)-allyl complexes (C5Me5)-RuCl2(η3-allyl) are easily prepared from a Ru(III) complex, [(C5Me5)RuCl2]n, by treatment with allylic halides, alcohol, ethers, acetate, or sulfides. Treatment of the resulting dichlororuthenium(IV) complex with aqueous HBr or HI solution resulted in smooth halogen-exchange reactions.

AB - Ruthenium(IV)-allyl complexes (C5Me5)-RuCl2(η3-allyl) are easily prepared from a Ru(III) complex, [(C5Me5)RuCl2]n, by treatment with allylic halides, alcohol, ethers, acetate, or sulfides. Treatment of the resulting dichlororuthenium(IV) complex with aqueous HBr or HI solution resulted in smooth halogen-exchange reactions.

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EP - 1315

JO - Organometallics

JF - Organometallics

IS - 7

ER -

A Convenient Route to Ruthenium(IV)-Allyl Complexes (C₅Me₅)RuX₂(η³-allyl) from [(C₅Me₅)RuCl₂]n

Abstract

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