A Convenient Route to Ruthenium(IV)-Allyl Complexes (C5Me5)RuX23-allyl) from [(C5Me5)RuCl2]n

Hideo Nagashima, Katsunori Mukai, Yusuke Shiota, Ken Ichi Ara, Kenji Itoh, Hiroharu Suzuki, Noriaki Oshima, Yoshihiko Moro-oka

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Abstract

Ruthenium(IV)-allyl complexes (C5Me5)-RuCl23-allyl) are easily prepared from a Ru(III) complex, [(C5Me5)RuCl2]n, by treatment with allylic halides, alcohol, ethers, acetate, or sulfides. Treatment of the resulting dichlororuthenium(IV) complex with aqueous HBr or HI solution resulted in smooth halogen-exchange reactions.

Original languageEnglish
Pages (from-to)1314-1315
Number of pages2
JournalOrganometallics
Volume4
Issue number7
DOIs
Publication statusPublished - Jul 1985
Externally publishedYes

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All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

Cite this

Nagashima, H., Mukai, K., Shiota, Y., Ara, K. I., Itoh, K., Suzuki, H., ... Moro-oka, Y. (1985). A Convenient Route to Ruthenium(IV)-Allyl Complexes (C5Me5)RuX23-allyl) from [(C5Me5)RuCl2]n. Organometallics, 4(7), 1314-1315. https://doi.org/10.1021/om00126a036