A Critical Study of Cu2O: Synthesis and Its Application in CO2 Reduction by Photochemical and Electrochemical Approaches

Sathya Mohan, Brahmari Honnappa, Ashil Augustin, Mariyappan Shanmugam, Chitiphon Chuaicham, Keiko Sasaki, Boopathy Ramasamy, Karthikeyan Sekar

Research output: Contribution to journalReview articlepeer-review

3 Citations (Scopus)

Abstract

Copper oxide (Cu2O) is a potential material as a catalyst for CO2 reduction. Cu2O nanos-tructures have many advantages, including interfacial charge separation and transportation, enhanced surface area, quantum efficiency, and feasibility of modification via composite development or integra-tion of the favorable surface functional groups. We cover the current advancements in the synthesis of Cu2O nanomaterials in various morphological dimensions and their photochemical and electrochemical applications, which complies with the physical enrichment of their enhanced activity in every application they are employed in. The scope of fresh designs, namely composites or the hierarchy of copper oxide nanostructures, and various ways to improve CO2 reduction performance are also discussed in this review. Photochemical and electrochemical CO2 transformations have received tremendous attention in the last few years, thanks to the growing interest in renewable sources of energy and green facile chemistry. The current review provides an idea of current photochemical and electrochemical carbon dioxide fixing techniques by using Cu2O-based materials. Carboxylation and carboxylative cyclization, yield valuable chemicals such as carboxylic acids and heterocyclic compounds. Radical ions, which are induced by photo-and electrochemical reactions, as well as other high-energy organic molecules, are regarded as essential mid-products in photochemical and electrochemical reactions with CO2. It has also been claimed that CO2 can be activated to form radical anions.

Original languageEnglish
Article number445
JournalCatalysts
Volume12
Issue number4
DOIs
Publication statusPublished - Apr 2022

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Environmental Science(all)
  • Physical and Theoretical Chemistry

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