A cyano-bridged single-chain magnet featuring alternate high- and low-spin manganese(III) porphyrins

Xi Chen, Shu Qi Wu, Ai Li Cui, Hui Zhong Kou

Research output: Contribution to journalArticlepeer-review

30 Citations (Scopus)

Abstract

The chains in complex [Mn(TPP)][Mn(TPP)(CN)2] (H2TPP = meso-tetra(4-phenyl)-porphyrin) demonstrate perfect linearity, and are well isolated with the nearest interchain Mn–Mn separation of 12.95 Å. Ferromagnetic coupling is present among adjacent Mn(III) ions, and single-chain magnet (SCM) behaviour is verified.

Original languageEnglish
Pages (from-to)2120-2122
Number of pages3
JournalChemical Communications
Volume50
Issue number17
DOIs
Publication statusPublished - Jan 30 2014
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Fingerprint

Dive into the research topics of 'A cyano-bridged single-chain magnet featuring alternate high- and low-spin manganese(III) porphyrins'. Together they form a unique fingerprint.

Cite this