A cyano-bridged single-chain magnet featuring alternate high- and low-spin manganese(III) porphyrins

Xi Chen; Shu Qi Wu; Ai Li Cui; Hui Zhong Kou

doi:10.1039/c3cc48117d

A cyano-bridged single-chain magnet featuring alternate high- and low-spin manganese(III) porphyrins

Xi Chen, Shu Qi Wu, Ai Li Cui, Hui Zhong Kou

Research output: Contribution to journal › Article › peer-review

32 Citations (Scopus)

Abstract

The chains in complex [Mn(TPP)][Mn(TPP)(CN)₂] (H₂TPP = meso-tetra(4-phenyl)-porphyrin) demonstrate perfect linearity, and are well isolated with the nearest interchain Mn–Mn separation of 12.95 Å. Ferromagnetic coupling is present among adjacent Mn(III) ions, and single-chain magnet (SCM) behaviour is verified.

Original language	English
Pages (from-to)	2120-2122
Number of pages	3
Journal	Chemical Communications
Volume	50
Issue number	17
DOIs	https://doi.org/10.1039/c3cc48117d
Publication status	Published - Jan 30 2014
Externally published	Yes

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/c3cc48117d

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abstract = "The chains in complex [Mn(TPP)][Mn(TPP)(CN)2] (H2TPP = meso-tetra(4-phenyl)-porphyrin) demonstrate perfect linearity, and are well isolated with the nearest interchain Mn–Mn separation of 12.95 {\AA}. Ferromagnetic coupling is present among adjacent Mn(III) ions, and single-chain magnet (SCM) behaviour is verified.",

author = "Xi Chen and Wu, {Shu Qi} and Cui, {Ai Li} and Kou, {Hui Zhong}",

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AU - Chen, Xi

AU - Wu, Shu Qi

AU - Cui, Ai Li

AU - Kou, Hui Zhong

PY - 2014/1/30

Y1 - 2014/1/30

N2 - The chains in complex [Mn(TPP)][Mn(TPP)(CN)2] (H2TPP = meso-tetra(4-phenyl)-porphyrin) demonstrate perfect linearity, and are well isolated with the nearest interchain Mn–Mn separation of 12.95 Å. Ferromagnetic coupling is present among adjacent Mn(III) ions, and single-chain magnet (SCM) behaviour is verified.

AB - The chains in complex [Mn(TPP)][Mn(TPP)(CN)2] (H2TPP = meso-tetra(4-phenyl)-porphyrin) demonstrate perfect linearity, and are well isolated with the nearest interchain Mn–Mn separation of 12.95 Å. Ferromagnetic coupling is present among adjacent Mn(III) ions, and single-chain magnet (SCM) behaviour is verified.

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DO - 10.1039/c3cc48117d

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SN - 1359-7345

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A cyano-bridged single-chain magnet featuring alternate high- and low-spin manganese(III) porphyrins

Abstract

All Science Journal Classification (ASJC) codes

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