A cyclic porphyrin trimer as a receptor for fullerenes

Guzmán Gil-Ramírez, Steven D. Karlen, Atsuomi Shundo, Kyriakos Porfyrakis, Yasuhiro Ito, G. Andrew D. Briggs, John J.L. Morton, Harry L. Anderson

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97 Citations (Scopus)

Abstract

(Equation Presented). A cyclic porphyrin trimer has been synthesized which has a high affinity for fullerenes. It forms 1:1 complexes with C60 and C70 with association constants of 2×106 and 2×108 M-1, respectively, in toluene. Its affinities for C86 and La@C82 are too strong to measure by fluorescence titration. The solvent dependence of the association constants shows that solvation of both the guest and the host influence the binding strength.

Original languageEnglish
Pages (from-to)3544-3547
Number of pages4
JournalOrganic Letters
Volume12
Issue number15
DOIs
Publication statusPublished - Aug 6 2010
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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  • Cite this

    Gil-Ramírez, G., Karlen, S. D., Shundo, A., Porfyrakis, K., Ito, Y., Briggs, G. A. D., Morton, J. J. L., & Anderson, H. L. (2010). A cyclic porphyrin trimer as a receptor for fullerenes. Organic Letters, 12(15), 3544-3547. https://doi.org/10.1021/ol101393h