A double-driven photoelectrochemical cell

Nao Terasaki; Keitaro Kakutani; Tsuyoshi Akiyama; Sunao Yamada

doi:10.1016/S0379-6779(03)00234-0

A double-driven photoelectrochemical cell

Nao Terasaki, Keitaro Kakutani, Tsuyoshi Akiyama, Sunao Yamada

Materials Science and Engineering, School of Engineering

Research output: Contribution to journal › Article

9 Citations (Scopus)

Abstract

A novel photoelectrochemical cell consisting of a set of organic thin films which generate photocurrents in opposite directions was fabricated. The polythiophene film containing 5,10,15,20-tetraphenylporphyrin (TPP) and fullerene (C₆₀) generated anodic photocurrents in the presence of ferrocene, while that containing TPP alone generated cathodic photocurrents under aerobic condition. The combination of these two film-modified electrodes showed a better cell performance than the simple sum of these two independent photoelectrochemical cells. A push-pull type, double-driven photoelectrochemical cell is proposed in this paper.

Original language	English
Pages (from-to)	511-514
Number of pages	4
Journal	Synthetic Metals
Volume	139
Issue number	2
DOIs	https://doi.org/10.1016/S0379-6779(03)00234-0
Publication status	Published - Sep 5 2003

All Science Journal Classification (ASJC) codes

Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering
Metals and Alloys
Materials Chemistry

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abstract = "A novel photoelectrochemical cell consisting of a set of organic thin films which generate photocurrents in opposite directions was fabricated. The polythiophene film containing 5,10,15,20-tetraphenylporphyrin (TPP) and fullerene (C60) generated anodic photocurrents in the presence of ferrocene, while that containing TPP alone generated cathodic photocurrents under aerobic condition. The combination of these two film-modified electrodes showed a better cell performance than the simple sum of these two independent photoelectrochemical cells. A push-pull type, double-driven photoelectrochemical cell is proposed in this paper.",

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T1 - A double-driven photoelectrochemical cell

AU - Terasaki, Nao

AU - Kakutani, Keitaro

AU - Akiyama, Tsuyoshi

AU - Yamada, Sunao

PY - 2003/9/5

Y1 - 2003/9/5

N2 - A novel photoelectrochemical cell consisting of a set of organic thin films which generate photocurrents in opposite directions was fabricated. The polythiophene film containing 5,10,15,20-tetraphenylporphyrin (TPP) and fullerene (C60) generated anodic photocurrents in the presence of ferrocene, while that containing TPP alone generated cathodic photocurrents under aerobic condition. The combination of these two film-modified electrodes showed a better cell performance than the simple sum of these two independent photoelectrochemical cells. A push-pull type, double-driven photoelectrochemical cell is proposed in this paper.

AB - A novel photoelectrochemical cell consisting of a set of organic thin films which generate photocurrents in opposite directions was fabricated. The polythiophene film containing 5,10,15,20-tetraphenylporphyrin (TPP) and fullerene (C60) generated anodic photocurrents in the presence of ferrocene, while that containing TPP alone generated cathodic photocurrents under aerobic condition. The combination of these two film-modified electrodes showed a better cell performance than the simple sum of these two independent photoelectrochemical cells. A push-pull type, double-driven photoelectrochemical cell is proposed in this paper.

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