A Dynamic Interface Based on Segregation of an Amphiphilic Hyperbranched Polymer Containing Fluoroalkyl and Oligo(ethylene oxide) Moieties

Yukari Oda; Manabu Inutsuka; Ryo Awane; Masayasu Totani; Norifumi L. Yamada; Masayuki Haraguchi; Masaaki Ozawa; Hisao Matsuno; Keiji Tanaka

doi:10.1021/acs.macromol.9b02064

A Dynamic Interface Based on Segregation of an Amphiphilic Hyperbranched Polymer Containing Fluoroalkyl and Oligo(ethylene oxide) Moieties

Yukari Oda, Manabu Inutsuka, Ryo Awane, Masayasu Totani, Norifumi L. Yamada, Masayuki Haraguchi, Masaaki Ozawa, Hisao Matsuno, Keiji Tanaka

Department of Applied Chemistry

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

An amphiphilic hyperbranched polymer (HBP) containing both fluoroalkyl (R_f:-C₆F₁₃) pendants and oligo(ethylene oxide) (nEO) parts was synthesized as a novel type of interfacial modifier to confer dynamic features on conventional polymer films. The HBP was always segregated at the outermost region of the polymer matrix in contact with air and water phases. The former and latter were driven by the presence of hydrophobic R_f pendants and hydrophilic nEO parts, respectively. Such a dynamic interface can be attained by changing the local conformation of HBP or segment-level segregation in the HBP molecule. In water, nEO parts formed a dissolved layer at the interface and induced excellent bioinert properties. Our strategy based on stable segregation, which could be maintained even after changing the environment, should be useful for constructing functional surfaces.

Original language	English
Pages (from-to)	2380-2387
Number of pages	8
Journal	Macromolecules
Volume	53
Issue number	7
DOIs	https://doi.org/10.1021/acs.macromol.9b02064
Publication status	Published - Apr 14 2020

All Science Journal Classification (ASJC) codes

Organic Chemistry
Polymers and Plastics
Inorganic Chemistry
Materials Chemistry

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10.1021/acs.macromol.9b02064

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title = "A Dynamic Interface Based on Segregation of an Amphiphilic Hyperbranched Polymer Containing Fluoroalkyl and Oligo(ethylene oxide) Moieties",

abstract = "An amphiphilic hyperbranched polymer (HBP) containing both fluoroalkyl (Rf:-C6F13) pendants and oligo(ethylene oxide) (nEO) parts was synthesized as a novel type of interfacial modifier to confer dynamic features on conventional polymer films. The HBP was always segregated at the outermost region of the polymer matrix in contact with air and water phases. The former and latter were driven by the presence of hydrophobic Rf pendants and hydrophilic nEO parts, respectively. Such a dynamic interface can be attained by changing the local conformation of HBP or segment-level segregation in the HBP molecule. In water, nEO parts formed a dissolved layer at the interface and induced excellent bioinert properties. Our strategy based on stable segregation, which could be maintained even after changing the environment, should be useful for constructing functional surfaces.",

author = "Yukari Oda and Manabu Inutsuka and Ryo Awane and Masayasu Totani and Yamada, {Norifumi L.} and Masayuki Haraguchi and Masaaki Ozawa and Hisao Matsuno and Keiji Tanaka",

note = "Funding Information: This research was partly supported by JSPS KAKENHI Grant-in-Aid for Young Scientists (B) (no. JP16K17917) to Y.O., and JST-Mirai Program (JPMJMI18A2) to K.T. NR measurements were performed on BL-16 at the Materials and Life Science Facility, J-PARC, Japan under program no. 2015A0238 and no. 2017L2500. Funding Information: This research was partly supported by JSPS KAKENHI, Grant-in-Aid for Young Scientists (B) (no. JP16K17917) to Y.O., and JST-Mirai Program (JPMJMI18A2) to K.T. NR measurements were performed on BL-16 at the Materials and Life Science Facility, J-PARC, Japan, under program no. 2015A0238 and no. 2017L2500.",

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doi = "10.1021/acs.macromol.9b02064",

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T1 - A Dynamic Interface Based on Segregation of an Amphiphilic Hyperbranched Polymer Containing Fluoroalkyl and Oligo(ethylene oxide) Moieties

AU - Oda, Yukari

AU - Inutsuka, Manabu

AU - Awane, Ryo

AU - Totani, Masayasu

AU - Yamada, Norifumi L.

AU - Haraguchi, Masayuki

AU - Ozawa, Masaaki

AU - Matsuno, Hisao

AU - Tanaka, Keiji

N1 - Funding Information: This research was partly supported by JSPS KAKENHI Grant-in-Aid for Young Scientists (B) (no. JP16K17917) to Y.O., and JST-Mirai Program (JPMJMI18A2) to K.T. NR measurements were performed on BL-16 at the Materials and Life Science Facility, J-PARC, Japan under program no. 2015A0238 and no. 2017L2500. Funding Information: This research was partly supported by JSPS KAKENHI, Grant-in-Aid for Young Scientists (B) (no. JP16K17917) to Y.O., and JST-Mirai Program (JPMJMI18A2) to K.T. NR measurements were performed on BL-16 at the Materials and Life Science Facility, J-PARC, Japan, under program no. 2015A0238 and no. 2017L2500.

PY - 2020/4/14

Y1 - 2020/4/14

N2 - An amphiphilic hyperbranched polymer (HBP) containing both fluoroalkyl (Rf:-C6F13) pendants and oligo(ethylene oxide) (nEO) parts was synthesized as a novel type of interfacial modifier to confer dynamic features on conventional polymer films. The HBP was always segregated at the outermost region of the polymer matrix in contact with air and water phases. The former and latter were driven by the presence of hydrophobic Rf pendants and hydrophilic nEO parts, respectively. Such a dynamic interface can be attained by changing the local conformation of HBP or segment-level segregation in the HBP molecule. In water, nEO parts formed a dissolved layer at the interface and induced excellent bioinert properties. Our strategy based on stable segregation, which could be maintained even after changing the environment, should be useful for constructing functional surfaces.

AB - An amphiphilic hyperbranched polymer (HBP) containing both fluoroalkyl (Rf:-C6F13) pendants and oligo(ethylene oxide) (nEO) parts was synthesized as a novel type of interfacial modifier to confer dynamic features on conventional polymer films. The HBP was always segregated at the outermost region of the polymer matrix in contact with air and water phases. The former and latter were driven by the presence of hydrophobic Rf pendants and hydrophilic nEO parts, respectively. Such a dynamic interface can be attained by changing the local conformation of HBP or segment-level segregation in the HBP molecule. In water, nEO parts formed a dissolved layer at the interface and induced excellent bioinert properties. Our strategy based on stable segregation, which could be maintained even after changing the environment, should be useful for constructing functional surfaces.

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A Dynamic Interface Based on Segregation of an Amphiphilic Hyperbranched Polymer Containing Fluoroalkyl and Oligo(ethylene oxide) Moieties

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