A flexible coordination polymer crystal providing reversible structural and magnetic conversions

Wakako Kaneko, Masaaki Ohba, Susumu Kitagawa

Research output: Contribution to journalArticle

177 Citations (Scopus)

Abstract

Structural flexibility is a remarkable characteristic of coordination polymers and significant for the attainment of environmental responsivity. We have prepared a 2D cyanide-bridged MnIICrIII coordination polymer, [Mn(NNdmenH)(H2O)][Cr(CN)6]·H2O (1; NNdmen = N,N-dimethylethylenediamine), with sophisticatedly arranged removable water coligands. The compound clearly showed a reversible single-crystal-to-single-crystal transformation between the 2D sheet and a 3D pillared-sheet framework of dehydrated [Mn(NNdmenH)][Cr(CN)6] (1a). The structural change was reversible and accompanied with generation/cleavage of CN-Mn bonds between 2D sheets by dehydration/hydration. Compounds 1 and 1a also exhibited a ferrimagnetic ordering at 35.2 and 60.4 K, respectively, and the magnetic characteristics were reversibly converted by guest adsorption/ desorption. In addition, the dehydrated 1a demonstrated a size-selective solvent adsorption linking chemi- and physisorption processes and shrinkage/expansion of its framework. The flexible magnetic framework incorporating removable coligands delivered multifunctions with chemical response.

Original languageEnglish
Pages (from-to)13706-13712
Number of pages7
JournalJournal of the American Chemical Society
Volume129
Issue number44
DOIs
Publication statusPublished - Nov 7 2007
Externally publishedYes

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Adsorption
Polymers
Single crystals
Crystals
Physisorption
Cyanides
Dehydration
Hydration
Desorption
Water
dimethylethylenediamine

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

Cite this

A flexible coordination polymer crystal providing reversible structural and magnetic conversions. / Kaneko, Wakako; Ohba, Masaaki; Kitagawa, Susumu.

In: Journal of the American Chemical Society, Vol. 129, No. 44, 07.11.2007, p. 13706-13712.

Research output: Contribution to journalArticle

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AB - Structural flexibility is a remarkable characteristic of coordination polymers and significant for the attainment of environmental responsivity. We have prepared a 2D cyanide-bridged MnIICrIII coordination polymer, [Mn(NNdmenH)(H2O)][Cr(CN)6]·H2O (1; NNdmen = N,N-dimethylethylenediamine), with sophisticatedly arranged removable water coligands. The compound clearly showed a reversible single-crystal-to-single-crystal transformation between the 2D sheet and a 3D pillared-sheet framework of dehydrated [Mn(NNdmenH)][Cr(CN)6] (1a). The structural change was reversible and accompanied with generation/cleavage of CN-Mn bonds between 2D sheets by dehydration/hydration. Compounds 1 and 1a also exhibited a ferrimagnetic ordering at 35.2 and 60.4 K, respectively, and the magnetic characteristics were reversibly converted by guest adsorption/ desorption. In addition, the dehydrated 1a demonstrated a size-selective solvent adsorption linking chemi- and physisorption processes and shrinkage/expansion of its framework. The flexible magnetic framework incorporating removable coligands delivered multifunctions with chemical response.

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