A head-to-head isomer of bis(μ-N-methyl-isonicotinamidato)bis[cis- diammineplatinum(II)] tetraperchlorate

Ken Sakai, Meiko Shiomi, Taro Tsubomura, Kaoru Kato, Yoshimi Yokoyama, Takashi Kajiwara, Tasuku Ito

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

In the title compound, [Pt2(C7H8N 2O)2(NH3)4](ClO4) 4), the head-to-head isomer of the PtII dimer has a mirror plane through the Pt-Pt bond axis. The intradimer Pt-Pt distance is 3.0569 (8) Å, while the shortest interdimer Pt⋯Pt distance is 7.2325 (9) Å. Two adjacent dimers are associated with one another, with a π-stacking interaction between the N-methyl-pyridinium moieties, where the plane-to-plane separation is 3.27 (1) Å.

Original languageEnglish
Pages (from-to)m559-m561
JournalActa Crystallographica Section E: Structure Reports Online
Volume59
Issue number8
DOIs
Publication statusPublished - Aug 1 2003
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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