A head-to-head isomer of di-μ-a-pyrrolidinonato-bis[cis-diammine- bromoplatinum(III)] dinitrate

Ken Sakai; Tomohiko Sakamoto; Takashi Kajiwara; Tasuku Ito

doi:10.1107/S1600536803014405

A head-to-head isomer of di-μ-a-pyrrolidinonato-bis[cis-diammine- bromoplatinum(III)] dinitrate

Ken Sakai, Tomohiko Sakamoto, Takashi Kajiwara, Tasuku Ito

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

In the title compound, [Pt₂Br₂(C₄H ₆NO)₂(NH₃)₄]NO₃) ₂, the intradimer Pt-Pt distance is 2.6476 (4) Å. The axial Pt^III-Br bond distances at the N^4- and N₂O ₂-coordinated sites are 2.5647 (9) and 2.5889 (8) Å, respectively. The two Pt coordination planes are tilted by 18.1 (3)°, and the average torsional twist of the ligands about the Pt-Pt axis is estimated as 1.0°.

Original language	English
Pages (from-to)	m553-m555
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	59
Issue number	7
DOIs	https://doi.org/10.1107/S1600536803014405
Publication status	Published - Jul 1 2003
Externally published	Yes

All Science Journal Classification (ASJC) codes

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

Access to Document

10.1107/S1600536803014405

Cite this

@article{f627ab4e7d8f40d2a780d6e23395b18a,

title = "A head-to-head isomer of di-μ-a-pyrrolidinonato-bis[cis-diammine- bromoplatinum(III)] dinitrate",

abstract = "In the title compound, [Pt2Br2(C4H 6NO)2(NH3)4]NO3) 2, the intradimer Pt-Pt distance is 2.6476 (4) {\AA}. The axial PtIII-Br bond distances at the N4- and N2O 2-coordinated sites are 2.5647 (9) and 2.5889 (8) {\AA}, respectively. The two Pt coordination planes are tilted by 18.1 (3)°, and the average torsional twist of the ligands about the Pt-Pt axis is estimated as 1.0°.",

author = "Ken Sakai and Tomohiko Sakamoto and Takashi Kajiwara and Tasuku Ito",

year = "2003",

month = jul,

day = "1",

doi = "10.1107/S1600536803014405",

language = "English",

volume = "59",

pages = "m553--m555",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "7",

}

TY - JOUR

T1 - A head-to-head isomer of di-μ-a-pyrrolidinonato-bis[cis-diammine- bromoplatinum(III)] dinitrate

AU - Sakai, Ken

AU - Sakamoto, Tomohiko

AU - Kajiwara, Takashi

AU - Ito, Tasuku

PY - 2003/7/1

Y1 - 2003/7/1

N2 - In the title compound, [Pt2Br2(C4H 6NO)2(NH3)4]NO3) 2, the intradimer Pt-Pt distance is 2.6476 (4) Å. The axial PtIII-Br bond distances at the N4- and N2O 2-coordinated sites are 2.5647 (9) and 2.5889 (8) Å, respectively. The two Pt coordination planes are tilted by 18.1 (3)°, and the average torsional twist of the ligands about the Pt-Pt axis is estimated as 1.0°.

AB - In the title compound, [Pt2Br2(C4H 6NO)2(NH3)4]NO3) 2, the intradimer Pt-Pt distance is 2.6476 (4) Å. The axial PtIII-Br bond distances at the N4- and N2O 2-coordinated sites are 2.5647 (9) and 2.5889 (8) Å, respectively. The two Pt coordination planes are tilted by 18.1 (3)°, and the average torsional twist of the ligands about the Pt-Pt axis is estimated as 1.0°.

UR - http://www.scopus.com/inward/record.url?scp=3142555703&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=3142555703&partnerID=8YFLogxK

U2 - 10.1107/S1600536803014405

DO - 10.1107/S1600536803014405

M3 - Article

AN - SCOPUS:3142555703

SN - 1600-5368

VL - 59

SP - m553-m555

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 7

ER -

A head-to-head isomer of di-μ-a-pyrrolidinonato-bis[cis-diammine- bromoplatinum(III)] dinitrate

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this