A head-to-head isomer of di-μ-a-pyrrolidinonato-bis[cis-diammine- bromoplatinum(III)] dinitrate

Ken Sakai, Tomohiko Sakamoto, Takashi Kajiwara, Tasuku Ito

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

In the title compound, [Pt2Br2(C4H 6NO)2(NH3)4]NO3) 2, the intradimer Pt-Pt distance is 2.6476 (4) Å. The axial PtIII-Br bond distances at the N4- and N2O 2-coordinated sites are 2.5647 (9) and 2.5889 (8) Å, respectively. The two Pt coordination planes are tilted by 18.1 (3)°, and the average torsional twist of the ligands about the Pt-Pt axis is estimated as 1.0°.

Original languageEnglish
Pages (from-to)m553-m555
JournalActa Crystallographica Section E: Structure Reports Online
Volume59
Issue number7
DOIs
Publication statusPublished - Jul 1 2003
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Fingerprint Dive into the research topics of 'A head-to-head isomer of di-μ-a-pyrrolidinonato-bis[cis-diammine- bromoplatinum(III)] dinitrate'. Together they form a unique fingerprint.

  • Cite this