A head-to-head isomer of di-μ-pivalamidato-k4N,O bis[(1,10-phenanthroline-k2N,N′)platiniim(Ii)] dinitrate dihydrate

Ken Sakai, Mai Kurashima, Norinobu Akiyama, Naoki Satoh, Takashi Kajiwara, Tasuku Ito

Research output: Contribution to journal › Article

7 Citations (Scopus)

Abstract

In the title compound, [Pt2(C5H10NO) 2(C12H8N2)2] (NO 3)2·2H2O, the intradimer Pt-Pt distance is relatively short [2.8489 (17) ̊], which must be due to the strong intramolecular π-π-stacking interactions between the phenanthroline moieties. The dimers stack along the c axis, forming one-dimensional columns in which very intriguing d-d, π-π and d-π interactions exist. Although the dimer-dimer Pt⋯Pt distances are very long [4.340 (2) and 4.231 (2) ̊], some short interdimer Pt⋯C contacts leading to strong interdimer associations are found [3.325 (19) and 3.402 (19) ̊].

Original languageEnglish
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume59
Issue number9
DOIs
Publication statusPublished - Sep 1 2003
Externally publishedYes

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Phenanthrolines
Isomers
Dimers
1,10-phenanthroline

All Science Journal Classification (ASJC) codes

  • Biochemistry, Genetics and Molecular Biology(all)

Cite this

A head-to-head isomer of di-μ-pivalamidato-k4N,O bis[(1,10-phenanthroline-k2N,N′)platiniim(Ii)] dinitrate dihydrate. / Sakai, Ken; Kurashima, Mai; Akiyama, Norinobu; Satoh, Naoki; Kajiwara, Takashi; Ito, Tasuku.

In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 59, No. 9, 01.09.2003.

Research output: Contribution to journal › Article

Sakai, K, Kurashima, M, Akiyama, N, Satoh, N, Kajiwara, T & Ito, T 2003, 'A head-to-head isomer of di-μ-pivalamidato-k4N,O bis[(1,10-phenanthroline-k2N,N′)platiniim(Ii)] dinitrate dihydrate', Acta Crystallographica Section C: Crystal Structure Communications, vol. 59, no. 9. https://doi.org/10.1107/S0108270103015920
Sakai K, Kurashima M, Akiyama N, Satoh N, Kajiwara T, Ito T. A head-to-head isomer of di-μ-pivalamidato-k4N,O bis[(1,10-phenanthroline-k2N,N′)platiniim(Ii)] dinitrate dihydrate. Acta Crystallographica Section C: Crystal Structure Communications. 2003 Sep 1;59(9). https://doi.org/10.1107/S0108270103015920
Sakai, Ken ; Kurashima, Mai ; Akiyama, Norinobu ; Satoh, Naoki ; Kajiwara, Takashi ; Ito, Tasuku. / A head-to-head isomer of di-μ-pivalamidato-k4N,O bis[(1,10-phenanthroline-k2N,N′)platiniim(Ii)] dinitrate dihydrate. In: Acta Crystallographica Section C: Crystal Structure Communications. 2003 ; Vol. 59, No. 9.
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abstract = "In the title compound, [Pt2(C5H10NO) 2(C12H8N2)2] (NO 3)2·2H2O, the intradimer Pt-Pt distance is relatively short [2.8489 (17) ̊], which must be due to the strong intramolecular π-π-stacking interactions between the phenanthroline moieties. The dimers stack along the c axis, forming one-dimensional columns in which very intriguing d-d, π-π and d-π interactions exist. Although the dimer-dimer Pt⋯Pt distances are very long [4.340 (2) and 4.231 (2) ̊], some short interdimer Pt⋯C contacts leading to strong interdimer associations are found [3.325 (19) and 3.402 (19) ̊].",
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T1 - A head-to-head isomer of di-μ-pivalamidato-k4N,O bis[(1,10-phenanthroline-k2N,N′)platiniim(Ii)] dinitrate dihydrate

AU - Sakai, Ken

AU - Kurashima, Mai

AU - Akiyama, Norinobu

AU - Satoh, Naoki

AU - Kajiwara, Takashi

AU - Ito, Tasuku

PY - 2003/9/1

Y1 - 2003/9/1

N2 - In the title compound, [Pt2(C5H10NO) 2(C12H8N2)2] (NO 3)2·2H2O, the intradimer Pt-Pt distance is relatively short [2.8489 (17) ̊], which must be due to the strong intramolecular π-π-stacking interactions between the phenanthroline moieties. The dimers stack along the c axis, forming one-dimensional columns in which very intriguing d-d, π-π and d-π interactions exist. Although the dimer-dimer Pt⋯Pt distances are very long [4.340 (2) and 4.231 (2) ̊], some short interdimer Pt⋯C contacts leading to strong interdimer associations are found [3.325 (19) and 3.402 (19) ̊].

AB - In the title compound, [Pt2(C5H10NO) 2(C12H8N2)2] (NO 3)2·2H2O, the intradimer Pt-Pt distance is relatively short [2.8489 (17) ̊], which must be due to the strong intramolecular π-π-stacking interactions between the phenanthroline moieties. The dimers stack along the c axis, forming one-dimensional columns in which very intriguing d-d, π-π and d-π interactions exist. Although the dimer-dimer Pt⋯Pt distances are very long [4.340 (2) and 4.231 (2) ̊], some short interdimer Pt⋯C contacts leading to strong interdimer associations are found [3.325 (19) and 3.402 (19) ̊].

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