Abstract
In the title compound, [Pt2(C5H10NO) 2(C12H8N2)2] (NO 3)2·2H2O, the intradimer Pt-Pt distance is relatively short [2.8489 (17) ̊], which must be due to the strong intramolecular π-π-stacking interactions between the phenanthroline moieties. The dimers stack along the c axis, forming one-dimensional columns in which very intriguing d-d, π-π and d-π interactions exist. Although the dimer-dimer Pt⋯Pt distances are very long [4.340 (2) and 4.231 (2) ̊], some short interdimer Pt⋯C contacts leading to strong interdimer associations are found [3.325 (19) and 3.402 (19) ̊].
| Original language | English |
|---|---|
| Pages (from-to) | m345-m349 |
| Journal | Acta Crystallographica Section C: Crystal Structure Communications |
| Volume | 59 |
| Issue number | 9 |
| DOIs | |
| Publication status | Published - Sep 1 2003 |
| Externally published | Yes |
All Science Journal Classification (ASJC) codes
- Biochemistry, Genetics and Molecular Biology(all)
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Sakai, K., Kurashima, M., Akiyama, N., Satoh, N., Kajiwara, T., & Ito, T. (2003). A head-to-head isomer of di-μ-pivalamidato-k4N,O bis[(1,10-phenanthroline-k2N,N′)platiniim(Ii)] dinitrate dihydrate. Acta Crystallographica Section C: Crystal Structure Communications, 59(9), m345-m349. https://doi.org/10.1107/S0108270103015920