TY - JOUR
T1 - A head-to-head isomer of di-μ-pivalamidato-k4N,O bis[(1,10-phenanthroline-k2N,N′)platiniim(Ii)] dinitrate dihydrate
AU - Sakai, Ken
AU - Kurashima, Mai
AU - Akiyama, Norinobu
AU - Satoh, Naoki
AU - Kajiwara, Takashi
AU - Ito, Tasuku
PY - 2003/9/1
Y1 - 2003/9/1
N2 - In the title compound, [Pt2(C5H10NO) 2(C12H8N2)2] (NO 3)2·2H2O, the intradimer Pt-Pt distance is relatively short [2.8489 (17) ̊], which must be due to the strong intramolecular π-π-stacking interactions between the phenanthroline moieties. The dimers stack along the c axis, forming one-dimensional columns in which very intriguing d-d, π-π and d-π interactions exist. Although the dimer-dimer Pt⋯Pt distances are very long [4.340 (2) and 4.231 (2) ̊], some short interdimer Pt⋯C contacts leading to strong interdimer associations are found [3.325 (19) and 3.402 (19) ̊].
AB - In the title compound, [Pt2(C5H10NO) 2(C12H8N2)2] (NO 3)2·2H2O, the intradimer Pt-Pt distance is relatively short [2.8489 (17) ̊], which must be due to the strong intramolecular π-π-stacking interactions between the phenanthroline moieties. The dimers stack along the c axis, forming one-dimensional columns in which very intriguing d-d, π-π and d-π interactions exist. Although the dimer-dimer Pt⋯Pt distances are very long [4.340 (2) and 4.231 (2) ̊], some short interdimer Pt⋯C contacts leading to strong interdimer associations are found [3.325 (19) and 3.402 (19) ̊].
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U2 - 10.1107/S0108270103015920
DO - 10.1107/S0108270103015920
M3 - Article
C2 - 12944640
AN - SCOPUS:0141863223
VL - 59
SP - m345-m349
JO - Acta Crystallographica Section C: Crystal Structure Communications
JF - Acta Crystallographica Section C: Crystal Structure Communications
SN - 0108-2701
IS - 9
ER -