A highly durable fuel cell electrocatalyst based on polybenzimidazole- coated stacked graphene

Tsuyohiko Fujigaya, Shinsuke Hirata, Naotoshi Nakashima

Research output: Contribution to journalArticle

36 Citations (Scopus)

Abstract

We describe here the finding that, with the aid of poly(benzimidazole) (PBI), soluble graphene was obtained in solution by the exfoliation of graphite without introducing oxidative sites on graphene, and the homogeneous loading of Pt-nanoparticles onto the PBI-covered non-oxidized graphene was successful. The prepared electrocatalyst showed very high electrochemical durability; namely, the electrochemical surface area of the catalyst was not much different even after 2000-cyclic voltammogram (CV) cyclings, which is because there was no formation of Pt aggregates after CV cyclings. The durability of the synthesized fuel cell catalyst was much higher than that of the conventional Pt-loaded carbon black catalyst. The design of such high performance graphene-based fuel cell electrocatalysts is important for the development of next-generation polymer electrolyte fuel cells.

Original languageEnglish
Pages (from-to)3888-3893
Number of pages6
JournalJournal of Materials Chemistry A
Volume2
Issue number11
DOIs
Publication statusPublished - Mar 21 2014

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Electrocatalysts
Graphene
Fuel cells
Catalysts
Durability
Soot
Carbon black
Electrolytes
Nanoparticles
Polymers

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Renewable Energy, Sustainability and the Environment
  • Materials Science(all)

Cite this

A highly durable fuel cell electrocatalyst based on polybenzimidazole- coated stacked graphene. / Fujigaya, Tsuyohiko; Hirata, Shinsuke; Nakashima, Naotoshi.

In: Journal of Materials Chemistry A, Vol. 2, No. 11, 21.03.2014, p. 3888-3893.

Research output: Contribution to journalArticle

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