A liquid crystalline chirality balance for vapours

Takuya Ohzono, Takahiro Yamamoto, Jun Ichi Fukuda

Research output: Contribution to journalArticle

24 Citations (Scopus)

Abstract

Chiral discrimination of vapours plays an important role in olfactory perception of biological systems and its realization by artificial sensors has been an intriguing challenge. Here, we report a simple method that tangibly visualizes the chirality of a diverse variety of molecules dissolved from vapours with high sensitivity, by making use of a structural change in a periodic microstructure of a nematic liquid crystal confined in open microchannels. This microstructure is accompanied by a topological line defect of a zigzag form with equal lengths of 'zig' and 'zag.' We find that a tiny amount of vapour of chiral molecules injected onto the liquid crystal induces the imbalance of 'zig' and 'zag' depending on its enantiomeric excess within a few seconds. Our liquid-crystal-based 'chirality balance' offers a simple, quick and versatile chirality-sensing/-screening method for gas-phase analysis (for example, for odours, environmental chemicals or drugs).

Original languageEnglish
Article number3735
JournalNature communications
Volume5
DOIs
Publication statusPublished - Apr 30 2014
Externally publishedYes

Fingerprint

Liquid Crystals
Chirality
chirality
Vapors
liquid crystals
vapors
Crystalline materials
Liquids
Olfactory Perception
liquids
olfactory perception
odors
microstructure
Microstructure
Molecules
Nematic liquid crystals
Odors
Biological systems
microchannels
Microchannels

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Biochemistry, Genetics and Molecular Biology(all)
  • Physics and Astronomy(all)

Cite this

A liquid crystalline chirality balance for vapours. / Ohzono, Takuya; Yamamoto, Takahiro; Fukuda, Jun Ichi.

In: Nature communications, Vol. 5, 3735, 30.04.2014.

Research output: Contribution to journalArticle

Ohzono, Takuya ; Yamamoto, Takahiro ; Fukuda, Jun Ichi. / A liquid crystalline chirality balance for vapours. In: Nature communications. 2014 ; Vol. 5.
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