A macrocyclic tetraamine bearing four phenol groups: a new class of heptadentate ligands to provide an oxygen-sensitive luminescent Tb(iii) complex with an extendable phenol pendant arm

Hidetaka Nakai, Kyoshiro Nonaka, Takahiro Goto, Juncheol Seo, Takahiro Matsumoto, Seiji Ogo

    Research output: Contribution to journalArticlepeer-review

    7 Citations (Scopus)

    Abstract

    This paper presents a 1,4,7,10-teraazacyclododecane-based tetrakis-phenol as a protonated ligand precursor and its oxygen-sensitive luminescent terbium(iii) complex with an extendable phenol pendant arm (Φ = 0.91 under N2, Φ = 0.031 under air), in which the potentially N4O4-octadentate ligand unprecedentedly coordinates to the Tb3+ ion in a N4O3-heptadentate fashion.

    Original languageEnglish
    Pages (from-to)10923-10927
    Number of pages5
    JournalDalton Transactions
    Volume44
    Issue number24
    DOIs
    Publication statusPublished - Jun 28 2015

    All Science Journal Classification (ASJC) codes

    • Inorganic Chemistry

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