A mer-Triaqua Rh complex with a terpyridine ligand

Daisuke Inoki, Takahiro Matsumoto, Hidetaka Nakai, Seiji Ogo

Research output: Contribution to journalArticle

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Abstract

We report the synthesis of a mer-triaqua Rh III complex using terpyridine as a meridional tridentate ligand. This is the first example of a structurally characterized six-coordinated mertriaqua complex for any second- or third-row element from the main transition-metal groups (groups 511). This is also the first example of a structurally characterized mer-triaqua complex with terpyridine for any transition metal. Acid dissociation constants, pK a1 and pK a2, of the triaqua complex are determined to be 3.0 and 6.9, respectively.

Original languageEnglish
Pages (from-to)116-118
Number of pages3
JournalChemistry Letters
Volume41
Issue number1
DOIs
Publication statusPublished - Jan 6 2012

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Transition metals
Ligands
Chemical elements
Acids

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

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A mer-Triaqua Rh complex with a terpyridine ligand. / Inoki, Daisuke; Matsumoto, Takahiro; Nakai, Hidetaka; Ogo, Seiji.

In: Chemistry Letters, Vol. 41, No. 1, 06.01.2012, p. 116-118.

Research output: Contribution to journalArticle

Inoki, Daisuke ; Matsumoto, Takahiro ; Nakai, Hidetaka ; Ogo, Seiji. / A mer-Triaqua Rh complex with a terpyridine ligand. In: Chemistry Letters. 2012 ; Vol. 41, No. 1. pp. 116-118.
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