A migrating group in a glutamate mutase model reaction mediated by a functionalised bilayer membrane

Yukito Murakami, Yoshio Hisaeda, Xi Ming Song, Teruhisa Ohno

Research output: Contribution to journalArticle

13 Citations (Scopus)

Abstract

The alkylated hydrophobic vitamin B12, prepared by the reaction of heptapropyl cobyrinate with diethyl β-bromomethyl-β-deuterio-DL- aspartate, affords diethyl γ-deuterioglutamate, the glycylmigrated product in the single-compartment vesicle of N,N-dihexadecyl-Nα-[6- (trimethylammonio)hexanoyl]-L-alaninamide bromide under anaerobic photolysis conditions.

Original languageEnglish
Pages (from-to)1527-1528
Number of pages2
JournalJournal of the Chemical Society, Perkin Transactions 2
Issue number9
Publication statusPublished - Dec 1 1992

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

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