A nanotube of cyclic porphyrin dimers connected by nonclassical hydrogen bonds and its inclusion of C60 in a linear arrangement

Hirofumi Nobukuni; Yuichi Shimazaki; Fumito Tani; Yoshinori Naruta

doi:10.1002/anie.200704058

A nanotube of cyclic porphyrin dimers connected by nonclassical hydrogen bonds and its inclusion of C₆₀ in a linear arrangement

Hirofumi Nobukuni, Yuichi Shimazaki, Fumito Tani, Yoshinori Naruta

Applied Molecular Chemistry

Research output: Contribution to journal › Article

85 Citations (Scopus)

Abstract

(Figure Presented) Like peas in a pod: X-ray crystallography reveals a self-assembled nanotube of cyclic porphyrin dimers and its inclusion complex with C₆₀ (see picture, N blue, Ni green). The cyclic molecules stack through nonclassical C-H⋯N hydrogen bonds and π-π interactions of pyridyl groups to form the tubular structure. The C₆₀ molecules are linearly arranged to form a supramolecular peapod.

Original language	English
Pages (from-to)	8975-8978
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	46
Issue number	47
DOIs	https://doi.org/10.1002/anie.200704058
Publication status	Published - Dec 14 2007

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Porphyrins

Dimers

Nanotubes

Hydrogen bonds

Molecules

X ray crystallography

All Science Journal Classification (ASJC) codes

Catalysis
Chemistry(all)

Cite this

Nobukuni, H., Shimazaki, Y., Tani, F., & Naruta, Y. (2007). A nanotube of cyclic porphyrin dimers connected by nonclassical hydrogen bonds and its inclusion of C₆₀ in a linear arrangement. Angewandte Chemie - International Edition, 46(47), 8975-8978. https://doi.org/10.1002/anie.200704058

A nanotube of cyclic porphyrin dimers connected by nonclassical hydrogen bonds and its inclusion of C₆₀ in a linear arrangement. / Nobukuni, Hirofumi; Shimazaki, Yuichi; Tani, Fumito; Naruta, Yoshinori.

In: Angewandte Chemie - International Edition, Vol. 46, No. 47, 14.12.2007, p. 8975-8978.

Research output: Contribution to journal › Article

Nobukuni, H, Shimazaki, Y, Tani, F & Naruta, Y 2007, 'A nanotube of cyclic porphyrin dimers connected by nonclassical hydrogen bonds and its inclusion of C₆₀ in a linear arrangement', Angewandte Chemie - International Edition, vol. 46, no. 47, pp. 8975-8978. https://doi.org/10.1002/anie.200704058

Nobukuni H, Shimazaki Y, Tani F, Naruta Y. A nanotube of cyclic porphyrin dimers connected by nonclassical hydrogen bonds and its inclusion of C₆₀ in a linear arrangement. Angewandte Chemie - International Edition. 2007 Dec 14;46(47):8975-8978. https://doi.org/10.1002/anie.200704058

Nobukuni, Hirofumi ; Shimazaki, Yuichi ; Tani, Fumito ; Naruta, Yoshinori. / A nanotube of cyclic porphyrin dimers connected by nonclassical hydrogen bonds and its inclusion of C₆₀ in a linear arrangement. In: Angewandte Chemie - International Edition. 2007 ; Vol. 46, No. 47. pp. 8975-8978.

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10.1002/anie.200704058