A naphthyl-substituted pentamethylcyclopentadienyl ligand and its Sm(ii) bent-metallocene complexes with solvent-induced structure change

Takeshi Yatabe, Masaki Karasawa, Kiyoshi Isobe, Seiji Ogo, Hidetaka Nakai

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

A naphthyl-substituted pentamethylcyclopentadienyl ligand (Cp Naph = η 5-C 5Me 4CH 2C 10H 7) and its Sm(ii) complexes [Sm(Cp Naph) 2(THF) x] (1: x = 2, 2: x = 0) have been prepared and characterised. The solvent-induced reversible conversion between the di-THF solvated purple complex 1 and the un-solvated dark green complex 2 is presented.

Original languageEnglish
Pages (from-to)354-356
Number of pages3
JournalDalton Transactions
Volume41
Issue number2
DOIs
Publication statusPublished - Jan 14 2012

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Ligands
metallocene

All Science Journal Classification (ASJC) codes

  • Inorganic Chemistry

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A naphthyl-substituted pentamethylcyclopentadienyl ligand and its Sm(ii) bent-metallocene complexes with solvent-induced structure change. / Yatabe, Takeshi; Karasawa, Masaki; Isobe, Kiyoshi; Ogo, Seiji; Nakai, Hidetaka.

In: Dalton Transactions, Vol. 41, No. 2, 14.01.2012, p. 354-356.

Research output: Contribution to journalArticle

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