A naphthyl-substituted pentamethylcyclopentadienyl ligand and its Sm(ii) bent-metallocene complexes with solvent-induced structure change

Takeshi Yatabe, Masaki Karasawa, Kiyoshi Isobe, Seiji Ogo, Hidetaka Nakai

    Research output: Contribution to journalArticlepeer-review

    7 Citations (Scopus)

    Abstract

    A naphthyl-substituted pentamethylcyclopentadienyl ligand (Cp Naph = η 5-C 5Me 4CH 2C 10H 7) and its Sm(ii) complexes [Sm(Cp Naph) 2(THF) x] (1: x = 2, 2: x = 0) have been prepared and characterised. The solvent-induced reversible conversion between the di-THF solvated purple complex 1 and the un-solvated dark green complex 2 is presented.

    Original languageEnglish
    Pages (from-to)354-356
    Number of pages3
    JournalDalton Transactions
    Volume41
    Issue number2
    DOIs
    Publication statusPublished - Jan 14 2012

    All Science Journal Classification (ASJC) codes

    • Inorganic Chemistry

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