A neutral five-coordinated organoruthenium(0) complex: X-ray structure and unique solvatochromism

Kihun Jeong, Harutaka Nakamori, Shunsuke Imai, Takahiro Matsumoto, Seiji Ogo, Hidetaka Nakai

    Research output: Contribution to journalReview articlepeer-review

    1 Citation (Scopus)

    Abstract

    The structure of a neutral five-coordinated organoruthenium( 0) complex [(η 6-C 6Me 6)Ru 0(bpy)] (1, bpy: 2,2′-bipyridine) was determined by X-ray diffraction analysis. The solvent-induced reversible color change based on the interconversion between the purple Ru 0 complex 1 and a yellow Ru IIhydride complex [(η 6-C 6Me 6)Ru II(bpy)H] + is presented.

    Original languageEnglish
    Pages (from-to)650-651
    Number of pages2
    JournalChemistry Letters
    Volume41
    Issue number6
    DOIs
    Publication statusPublished - 2012

    All Science Journal Classification (ASJC) codes

    • Chemistry(all)

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