A New Design Strategy for Efficient Thermally Activated Delayed Fluorescence Organic Emitters: From Twisted to Planar Structures

Xian Kai Chen, Youichi Tsuchiya, Yuma Ishikawa, Cheng Zhong, Chihaya Adachi, Jean Luc Brédas

Research output: Contribution to journalArticle

62 Citations (Scopus)

Abstract

In the traditional molecular design of thermally activated delayed fluorescence (TADF) emitters composed of electron-donor and electron-acceptor moieties, achieving a small singlet–triplet energy gap (ΔEST) in strongly twisted structures usually translates into a small fluorescence oscillator strength, which can significantly decrease the emission quantum yield and limit efficiency in organic light-emitting diode devices. Here, based on the results of quantum-chemical calculations on TADF emitters composed of carbazole donor and 2,4,6-triphenyl-1,3,5-triazine acceptor moieties, a new strategy is proposed for the molecular design of efficient TADF emitters that combine a small ΔEST with a large fluorescence oscillator strength. Since this strategy goes beyond the traditional framework of structurally twisted, charge-transfer type emitters, importantly, it opens the way for coplanar molecules to be efficient TADF emitters. Here, a new emitter, composed of azatriangulene and diphenyltriazine moieties, is theoretically designed, which is coplanar due to intramolecular H-bonding interactions. The synthesis of this hexamethylazatriangulene-triazine (HMAT-TRZ) emitter and its preliminary photophysical characterizations point to HMAT-TRZ as a potential efficient TADF emitter.

Original languageEnglish
Article number1702767
JournalAdvanced Materials
Volume29
Issue number46
DOIs
Publication statusPublished - Dec 13 2017

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Fluorescence
Triazines
Electrons
Organic light emitting diodes (OLED)
Quantum yield
Charge transfer
Energy gap
Molecules

All Science Journal Classification (ASJC) codes

  • Materials Science(all)
  • Mechanics of Materials
  • Mechanical Engineering

Cite this

A New Design Strategy for Efficient Thermally Activated Delayed Fluorescence Organic Emitters : From Twisted to Planar Structures. / Chen, Xian Kai; Tsuchiya, Youichi; Ishikawa, Yuma; Zhong, Cheng; Adachi, Chihaya; Brédas, Jean Luc.

In: Advanced Materials, Vol. 29, No. 46, 1702767, 13.12.2017.

Research output: Contribution to journalArticle

Chen, Xian Kai ; Tsuchiya, Youichi ; Ishikawa, Yuma ; Zhong, Cheng ; Adachi, Chihaya ; Brédas, Jean Luc. / A New Design Strategy for Efficient Thermally Activated Delayed Fluorescence Organic Emitters : From Twisted to Planar Structures. In: Advanced Materials. 2017 ; Vol. 29, No. 46.
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