A new manganese coordination polymer involving in situ generated formate Dedicated to Prof. Xinquan Xin on the occasion of his 80th birthday.

Yongbing Lou, Yinhua Tao, Jingjing Wang, Jinxi Chen, Masaaki Ohba

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

A new three-dimensional (3D) manganese coordination polymer, [Mn 2(IP)1.5(HCOO)(DEF)]n (1) (H2IP = isophthalic acid, DEF = N,N-diethylformamide), has been solvothermally synthesized in DEF. X-ray single crystal structural data reveal that compound 1 crystallizes in orthorhombic space group Fdd2 and was constructed with infinite zig-zag chains of corner- and edge-sharing octahedral (MnO6) n units interconnected by isophthalate to form a 3D framework. The in situ generated formate ions from the hydrolysis of DEF adopt a special bridging mode to build the secondary building units (SBUs). Variable-temperature magnetic susceptibility of compound 1 exhibits overall weak antiferromagnetic coupling between the adjacent Mn2+ ions.

Original languageEnglish
Pages (from-to)72-76
Number of pages5
JournalPolyhedron
Volume73
DOIs
Publication statusPublished - May 8 2014

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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