TY - JOUR
T1 - A new manganese coordination polymer involving in situ generated formate Dedicated to Prof. Xinquan Xin on the occasion of his 80th birthday.
AU - Lou, Yongbing
AU - Tao, Yinhua
AU - Wang, Jingjing
AU - Chen, Jinxi
AU - Ohba, Masaaki
N1 - Funding Information:
This project was sponsored by the Natural Science Foundation of Jiangsu Province ( No. BK2009262 ). M.O. thanks the Grant-In-Aid for Science Research in a Priority Area ‘Coordination Programming (No. 22108512)’ and the Grant-In-Aid for Scientific Research Program (No. 23245014).
PY - 2014/5/8
Y1 - 2014/5/8
N2 - A new three-dimensional (3D) manganese coordination polymer, [Mn 2(IP)1.5(HCOO)(DEF)]n (1) (H2IP = isophthalic acid, DEF = N,N-diethylformamide), has been solvothermally synthesized in DEF. X-ray single crystal structural data reveal that compound 1 crystallizes in orthorhombic space group Fdd2 and was constructed with infinite zig-zag chains of corner- and edge-sharing octahedral (MnO6) n units interconnected by isophthalate to form a 3D framework. The in situ generated formate ions from the hydrolysis of DEF adopt a special bridging mode to build the secondary building units (SBUs). Variable-temperature magnetic susceptibility of compound 1 exhibits overall weak antiferromagnetic coupling between the adjacent Mn2+ ions.
AB - A new three-dimensional (3D) manganese coordination polymer, [Mn 2(IP)1.5(HCOO)(DEF)]n (1) (H2IP = isophthalic acid, DEF = N,N-diethylformamide), has been solvothermally synthesized in DEF. X-ray single crystal structural data reveal that compound 1 crystallizes in orthorhombic space group Fdd2 and was constructed with infinite zig-zag chains of corner- and edge-sharing octahedral (MnO6) n units interconnected by isophthalate to form a 3D framework. The in situ generated formate ions from the hydrolysis of DEF adopt a special bridging mode to build the secondary building units (SBUs). Variable-temperature magnetic susceptibility of compound 1 exhibits overall weak antiferromagnetic coupling between the adjacent Mn2+ ions.
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U2 - 10.1016/j.poly.2014.02.028
DO - 10.1016/j.poly.2014.02.028
M3 - Article
AN - SCOPUS:84897826887
SN - 0277-5387
VL - 73
SP - 72
EP - 76
JO - Polyhedron
JF - Polyhedron
ER -