A new mononuclear iron(III) complex containing a peroxocarbonate ligand

Koji Hashimoto, Shigenori Nagatomo, Shuhei Fujinami, Hideki Furutachi, Seiji Ogo, Masatatsu Suzuki, Akira Uehara, Yonezo Maeda, Yoshihito Watanabe, Teizo Kitagawa

Research output: Contribution to journal › Article

49 Citations (Scopus)

Abstract

Stabilization of a peroxocarbonate ligand by formation of a five-membered chelate ring. The mononuclear peroxocarbonate complex 1 was prepared by the reaction of a bis(μ-hydroxo)diiron(III) complex with H2O2 and CO2. Compound 1 is the first crystallographically characterized transition metal complex with a peroxocarbonate ligand. Formation of the peroxocarbonate moiety in 1 proceeds by a nucleophilic addition of a peroxide anion to CO2. Hqn = quinaldic acid.

Original languageEnglish
Pages (from-to)1202-1205
Number of pages4
JournalAngewandte Chemie - International Edition
Volume41
Issue number7
DOIs
Publication statusPublished - Apr 2 2002
Externally publishedYes

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Iron
Ligands
Coordination Complexes
Peroxides
Metal complexes
Transition metals
Anions
Negative ions
Stabilization
Acids
quinaldic acid

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

Cite this

A new mononuclear iron(III) complex containing a peroxocarbonate ligand. / Hashimoto, Koji; Nagatomo, Shigenori; Fujinami, Shuhei; Furutachi, Hideki; Ogo, Seiji; Suzuki, Masatatsu; Uehara, Akira; Maeda, Yonezo; Watanabe, Yoshihito; Kitagawa, Teizo.

In: Angewandte Chemie - International Edition, Vol. 41, No. 7, 02.04.2002, p. 1202-1205.

Research output: Contribution to journal › Article

Hashimoto, K, Nagatomo, S, Fujinami, S, Furutachi, H, Ogo, S, Suzuki, M, Uehara, A, Maeda, Y, Watanabe, Y & Kitagawa, T 2002, 'A new mononuclear iron(III) complex containing a peroxocarbonate ligand', Angewandte Chemie - International Edition, vol. 41, no. 7, pp. 1202-1205. https://doi.org/10.1002/1521-3773(20020402)41:7<1202::AID-ANIE1202>3.0.CO;2-E
Hashimoto K, Nagatomo S, Fujinami S, Furutachi H, Ogo S, Suzuki M et al. A new mononuclear iron(III) complex containing a peroxocarbonate ligand. Angewandte Chemie - International Edition. 2002 Apr 2;41(7):1202-1205. https://doi.org/10.1002/1521-3773(20020402)41:7<1202::AID-ANIE1202>3.0.CO;2-E
Hashimoto, Koji ; Nagatomo, Shigenori ; Fujinami, Shuhei ; Furutachi, Hideki ; Ogo, Seiji ; Suzuki, Masatatsu ; Uehara, Akira ; Maeda, Yonezo ; Watanabe, Yoshihito ; Kitagawa, Teizo. / A new mononuclear iron(III) complex containing a peroxocarbonate ligand. In: Angewandte Chemie - International Edition. 2002 ; Vol. 41, No. 7. pp. 1202-1205.
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