Abstract
Stabilization of a peroxocarbonate ligand by formation of a five-membered chelate ring. The mononuclear peroxocarbonate complex 1 was prepared by the reaction of a bis(μ-hydroxo)diiron(III) complex with H2O2 and CO2. Compound 1 is the first crystallographically characterized transition metal complex with a peroxocarbonate ligand. Formation of the peroxocarbonate moiety in 1 proceeds by a nucleophilic addition of a peroxide anion to CO2. Hqn = quinaldic acid.
Original language | English |
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Pages (from-to) | 1202-1205 |
Number of pages | 4 |
Journal | Angewandte Chemie - International Edition |
Volume | 41 |
Issue number | 7 |
DOIs | |
Publication status | Published - Apr 2 2002 |
Externally published | Yes |
All Science Journal Classification (ASJC) codes
- Catalysis
- Chemistry(all)