A new mononuclear iron(III) complex containing a peroxocarbonate ligand

Koji Hashimoto, Shigenori Nagatomo, Shuhei Fujinami, Hideki Furutachi, Seiji Ogo, Masatatsu Suzuki, Akira Uehara, Yonezo Maeda, Yoshihito Watanabe, Teizo Kitagawa

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49 Citations (Scopus)

Abstract

Stabilization of a peroxocarbonate ligand by formation of a five-membered chelate ring. The mononuclear peroxocarbonate complex 1 was prepared by the reaction of a bis(μ-hydroxo)diiron(III) complex with H2O2 and CO2. Compound 1 is the first crystallographically characterized transition metal complex with a peroxocarbonate ligand. Formation of the peroxocarbonate moiety in 1 proceeds by a nucleophilic addition of a peroxide anion to CO2. Hqn = quinaldic acid.

Original languageEnglish
Pages (from-to)1202-1205
Number of pages4
JournalAngewandte Chemie - International Edition
Volume41
Issue number7
DOIs
Publication statusPublished - Apr 2 2002
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

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    Hashimoto, K., Nagatomo, S., Fujinami, S., Furutachi, H., Ogo, S., Suzuki, M., Uehara, A., Maeda, Y., Watanabe, Y., & Kitagawa, T. (2002). A new mononuclear iron(III) complex containing a peroxocarbonate ligand. Angewandte Chemie - International Edition, 41(7), 1202-1205. https://doi.org/10.1002/1521-3773(20020402)41:7<1202::AID-ANIE1202>3.0.CO;2-E