A new mononuclear iron(III) complex containing a peroxocarbonate ligand

Koji Hashimoto; Shigenori Nagatomo; Shuhei Fujinami; Hideki Furutachi; Seiji Ogo; Masatatsu Suzuki; Akira Uehara; Yonezo Maeda; Yoshihito Watanabe; Teizo Kitagawa

doi:10.1002/1521-3773(20020402)41:7<1202::AID-ANIE1202>3.0.CO;2-E

A new mononuclear iron(III) complex containing a peroxocarbonate ligand

Koji Hashimoto, Shigenori Nagatomo, Shuhei Fujinami, Hideki Furutachi, Seiji Ogo, Masatatsu Suzuki, Akira Uehara, Yonezo Maeda, Yoshihito Watanabe, Teizo Kitagawa

Research output: Contribution to journal › Article › peer-review

54 Citations (Scopus)

Abstract

Stabilization of a peroxocarbonate ligand by formation of a five-membered chelate ring. The mononuclear peroxocarbonate complex 1 was prepared by the reaction of a bis(μ-hydroxo)diiron(III) complex with H₂O₂ and CO₂. Compound 1 is the first crystallographically characterized transition metal complex with a peroxocarbonate ligand. Formation of the peroxocarbonate moiety in 1 proceeds by a nucleophilic addition of a peroxide anion to CO₂. Hqn = quinaldic acid.

Original language	English
Pages (from-to)	1202-1205
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	41
Issue number	7
DOIs	https://doi.org/10.1002/1521-3773(20020402)41:7<1202::AID-ANIE1202>3.0.CO;2-E
Publication status	Published - Apr 2 2002
Externally published	Yes

All Science Journal Classification (ASJC) codes

Catalysis
Chemistry(all)

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10.1002/1521-3773(20020402)41:7<1202::AID-ANIE1202>3.0.CO;2-E

Cite this

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title = "A new mononuclear iron(III) complex containing a peroxocarbonate ligand",

abstract = "Stabilization of a peroxocarbonate ligand by formation of a five-membered chelate ring. The mononuclear peroxocarbonate complex 1 was prepared by the reaction of a bis(μ-hydroxo)diiron(III) complex with H2O2 and CO2. Compound 1 is the first crystallographically characterized transition metal complex with a peroxocarbonate ligand. Formation of the peroxocarbonate moiety in 1 proceeds by a nucleophilic addition of a peroxide anion to CO2. Hqn = quinaldic acid.",

author = "Koji Hashimoto and Shigenori Nagatomo and Shuhei Fujinami and Hideki Furutachi and Seiji Ogo and Masatatsu Suzuki and Akira Uehara and Yonezo Maeda and Yoshihito Watanabe and Teizo Kitagawa",

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doi = "10.1002/1521-3773(20020402)41:7<1202::AID-ANIE1202>3.0.CO;2-E",

language = "English",

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TY - JOUR

T1 - A new mononuclear iron(III) complex containing a peroxocarbonate ligand

AU - Hashimoto, Koji

AU - Nagatomo, Shigenori

AU - Fujinami, Shuhei

AU - Furutachi, Hideki

AU - Ogo, Seiji

AU - Suzuki, Masatatsu

AU - Uehara, Akira

AU - Maeda, Yonezo

AU - Watanabe, Yoshihito

AU - Kitagawa, Teizo

PY - 2002/4/2

Y1 - 2002/4/2

N2 - Stabilization of a peroxocarbonate ligand by formation of a five-membered chelate ring. The mononuclear peroxocarbonate complex 1 was prepared by the reaction of a bis(μ-hydroxo)diiron(III) complex with H2O2 and CO2. Compound 1 is the first crystallographically characterized transition metal complex with a peroxocarbonate ligand. Formation of the peroxocarbonate moiety in 1 proceeds by a nucleophilic addition of a peroxide anion to CO2. Hqn = quinaldic acid.

AB - Stabilization of a peroxocarbonate ligand by formation of a five-membered chelate ring. The mononuclear peroxocarbonate complex 1 was prepared by the reaction of a bis(μ-hydroxo)diiron(III) complex with H2O2 and CO2. Compound 1 is the first crystallographically characterized transition metal complex with a peroxocarbonate ligand. Formation of the peroxocarbonate moiety in 1 proceeds by a nucleophilic addition of a peroxide anion to CO2. Hqn = quinaldic acid.

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DO - 10.1002/1521-3773(20020402)41:7<1202::AID-ANIE1202>3.0.CO;2-E

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

SN - 1433-7851

IS - 7

ER -

A new mononuclear iron(III) complex containing a peroxocarbonate ligand

Abstract

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