A new soluble 1,10-phenanthroline-containing π-conjugated polymer

Synthesis and effect of metal complexation on optical properties

Takuma Yasuda, Isao Yamaguchi, Takakazu Yamamoto

Research output: Contribution to journalArticle

95 Citations (Scopus)

Abstract

The π-Conjugated polymers containing the metal complexes of phen and bpy were said to be promising functional materials. However, the metal complex forming reactivity of these polymers and the optical properties of their metal complexes were not extensively analyzed, especially for non-substituted pphen, due to its poor solubility in organic solvents. Recently, soluble arylene ethynylene type π-conjugated polymers consisting of the phen unit and related low molecular compounds were synthesized, and their highly luminescent properties in solutions were revealed. This paper reports the preparation of a new, soluble phen-containing π-conjugated polymer 1 and its low molecular model compound 2, and their optical properties tuned by metal complexation.

Original languageEnglish
Pages (from-to)293-296
Number of pages4
JournalAdvanced Materials
Volume15
Issue number4
DOIs
Publication statusPublished - Feb 17 2003

Fingerprint

Coordination Complexes
Conjugated polymers
Metal complexes
Complexation
Optical properties
Metals
Functional materials
Organic solvents
Polymers
Solubility
1,10-phenanthroline

All Science Journal Classification (ASJC) codes

  • Materials Science(all)
  • Mechanics of Materials
  • Mechanical Engineering

Cite this

A new soluble 1,10-phenanthroline-containing π-conjugated polymer : Synthesis and effect of metal complexation on optical properties. / Yasuda, Takuma; Yamaguchi, Isao; Yamamoto, Takakazu.

In: Advanced Materials, Vol. 15, No. 4, 17.02.2003, p. 293-296.

Research output: Contribution to journalArticle

@article{b4e3ca11caba4bd7a7a4a8d4b0ab4b90,
title = "A new soluble 1,10-phenanthroline-containing π-conjugated polymer: Synthesis and effect of metal complexation on optical properties",
abstract = "The π-Conjugated polymers containing the metal complexes of phen and bpy were said to be promising functional materials. However, the metal complex forming reactivity of these polymers and the optical properties of their metal complexes were not extensively analyzed, especially for non-substituted pphen, due to its poor solubility in organic solvents. Recently, soluble arylene ethynylene type π-conjugated polymers consisting of the phen unit and related low molecular compounds were synthesized, and their highly luminescent properties in solutions were revealed. This paper reports the preparation of a new, soluble phen-containing π-conjugated polymer 1 and its low molecular model compound 2, and their optical properties tuned by metal complexation.",
author = "Takuma Yasuda and Isao Yamaguchi and Takakazu Yamamoto",
year = "2003",
month = "2",
day = "17",
doi = "10.1002/adma.200390070",
language = "English",
volume = "15",
pages = "293--296",
journal = "Advanced Materials",
issn = "0935-9648",
publisher = "Wiley-VCH Verlag",
number = "4",

}

TY - JOUR

T1 - A new soluble 1,10-phenanthroline-containing π-conjugated polymer

T2 - Synthesis and effect of metal complexation on optical properties

AU - Yasuda, Takuma

AU - Yamaguchi, Isao

AU - Yamamoto, Takakazu

PY - 2003/2/17

Y1 - 2003/2/17

N2 - The π-Conjugated polymers containing the metal complexes of phen and bpy were said to be promising functional materials. However, the metal complex forming reactivity of these polymers and the optical properties of their metal complexes were not extensively analyzed, especially for non-substituted pphen, due to its poor solubility in organic solvents. Recently, soluble arylene ethynylene type π-conjugated polymers consisting of the phen unit and related low molecular compounds were synthesized, and their highly luminescent properties in solutions were revealed. This paper reports the preparation of a new, soluble phen-containing π-conjugated polymer 1 and its low molecular model compound 2, and their optical properties tuned by metal complexation.

AB - The π-Conjugated polymers containing the metal complexes of phen and bpy were said to be promising functional materials. However, the metal complex forming reactivity of these polymers and the optical properties of their metal complexes were not extensively analyzed, especially for non-substituted pphen, due to its poor solubility in organic solvents. Recently, soluble arylene ethynylene type π-conjugated polymers consisting of the phen unit and related low molecular compounds were synthesized, and their highly luminescent properties in solutions were revealed. This paper reports the preparation of a new, soluble phen-containing π-conjugated polymer 1 and its low molecular model compound 2, and their optical properties tuned by metal complexation.

UR - http://www.scopus.com/inward/record.url?scp=0037450227&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0037450227&partnerID=8YFLogxK

U2 - 10.1002/adma.200390070

DO - 10.1002/adma.200390070

M3 - Article

VL - 15

SP - 293

EP - 296

JO - Advanced Materials

JF - Advanced Materials

SN - 0935-9648

IS - 4

ER -