A new water-soluble and acid-stable dinuclear organoiridium dinitrate complex

Bunsho Kure, Shunichi Fukuzumi, Seiji Ogo

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Abstract

A new water-soluble and acid-stable dinuclear organoiridium(III) dinitrate complex [{Cp*Ir(NO3)}2(μ-Cl)2] (1, Cp* = η5-C5Me5) was synthesized by the reaction of a water-insoluble organoiridium(III) complex [(Cp*IrCl)2(μ-Cl)2] (2) with two equivalents of AgBF4 in aqueous nitric acid (1 M HNO3/H2O) at 23°C for 12h. The structure of 1 with two monodentate NO3 - ligands is discussed in comparison with structure of a mononuclear organoiridium(III) complex with one monodentate and one bidentate NO 3- ligands, [Cp*Ir(NO3)2] (3).

Original languageEnglish
Pages (from-to)1468-1469
Number of pages2
JournalChemistry Letters
Volume36
Issue number12
DOIs
Publication statusPublished - Dec 5 2007

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All Science Journal Classification (ASJC) codes

  • Chemistry(all)

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