TY - JOUR
T1 - A (Ni-SIr)I model for [NiFe]hydrogenase
AU - Matsumoto, Takahiro
AU - Ando, Tatsuya
AU - Mori, Yuki
AU - Yatabe, Takeshi
AU - Nakai, Hidetaka
AU - Ogo, Seiji
N1 - Funding Information:
This work was supported by Grants-in-Aid: 26000008 (Specially promoted Research), 26810038 , 26410074 , 25620047 , 25248017 , and 24109016 from the Ministry of Education, Culture, Sports, Science, and Technology (MEXT), Japan , the World Premier International Research Centre Initiative (WPI) , and the Basic Research Programs CREST Type from JST , Japan.
Publisher Copyright:
© 2014 Elsevier B.V. All rights reserved.
PY - 2015/11/1
Y1 - 2015/11/1
N2 - We report the synthesis and characterization of a μ-hydroxo NiRu complex as a model for the active site of (Ni-SIr)I of [NiFe]hydrogenase. This is the first example of the (Ni-SIr)I model with a bridging hydroxo ligand between dimetal centers and an available coordination site on Ni center cis to the bridging hydroxo ligand. We have determined the structure of the (Ni-SIr)I model complex by X-ray analysis and reported reversible switching between the catalytically inactive (Ni-SIr)I and a catalytically active (Ni-SIr)II models.
AB - We report the synthesis and characterization of a μ-hydroxo NiRu complex as a model for the active site of (Ni-SIr)I of [NiFe]hydrogenase. This is the first example of the (Ni-SIr)I model with a bridging hydroxo ligand between dimetal centers and an available coordination site on Ni center cis to the bridging hydroxo ligand. We have determined the structure of the (Ni-SIr)I model complex by X-ray analysis and reported reversible switching between the catalytically inactive (Ni-SIr)I and a catalytically active (Ni-SIr)II models.
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U2 - 10.1016/j.jorganchem.2014.09.025
DO - 10.1016/j.jorganchem.2014.09.025
M3 - Article
AN - SCOPUS:84941600368
SN - 0022-328X
VL - 796
SP - 73
EP - 76
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
ER -