A [NiFe]hydrogenase model that catalyses the release of hydrogen from formic acid

Nga T. Nguyen; Yuki Mori; Takahiro Matsumoto; Takeshi Yatabe; Ryota Kabe; Hidetaka Nakai; Ki Seok Yoon; Seiji Ogo

doi:10.1039/c4cc05911e

A [NiFe]hydrogenase model that catalyses the release of hydrogen from formic acid

Nga T. Nguyen, Yuki Mori, Takahiro Matsumoto, Takeshi Yatabe, Ryota Kabe, Hidetaka Nakai, Ki Seok Yoon, Seiji Ogo

Center for Organic Photonics and Electronics Research(OPERA)

Research output: Contribution to journal › Article › peer-review

19 Citations (Scopus)

Abstract

We report the decomposition of formic acid to hydrogen and carbon dioxide, catalysed by a NiRu complex originally developed as a [NiFe]hydrogenase model. This is the first example of H₂ evolution, catalysed by a [NiFe]hydrogenase model, which does not require additional energy.

Original language	English
Pages (from-to)	13385-13387
Number of pages	3
Journal	Chemical Communications
Volume	50
Issue number	87
DOIs	https://doi.org/10.1039/c4cc05911e
Publication status	Published - Nov 11 2014

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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abstract = "We report the decomposition of formic acid to hydrogen and carbon dioxide, catalysed by a NiRu complex originally developed as a [NiFe]hydrogenase model. This is the first example of H2 evolution, catalysed by a [NiFe]hydrogenase model, which does not require additional energy.",

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AU - Nguyen, Nga T.

AU - Mori, Yuki

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AU - Yatabe, Takeshi

AU - Kabe, Ryota

AU - Nakai, Hidetaka

AU - Yoon, Ki Seok

AU - Ogo, Seiji

PY - 2014/11/11

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AB - We report the decomposition of formic acid to hydrogen and carbon dioxide, catalysed by a NiRu complex originally developed as a [NiFe]hydrogenase model. This is the first example of H2 evolution, catalysed by a [NiFe]hydrogenase model, which does not require additional energy.

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A [NiFe]hydrogenase model that catalyses the release of hydrogen from formic acid

Abstract

All Science Journal Classification (ASJC) codes

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